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While the outstanding stability of per- and polyfluoroalkyl substances (PFAS) paved the way for their widespread application in a huge variety of applications, it also resulted in their nickname "forever chemicals". The rising awareness for PFAS-related environmental and health concerns drives a discussion on the most effective ways to abate PFAS emissions into the environment, i.e. water, soil, and air, and remediation of contaminated matter. In order to address the knowledge gap regarding air pollution by PFAS, this minireview summarizes the current corpus of work in the field and outlines how catalysis can contribute to PFAS abatement in the gas phase. Beyond a mere collection of state-of-the-art knowledge, overarching challenges in catalytic PFAS removal are identified, spanning from fundamental organic and inorganic chemistry, i.e. C-F-bond activation, to heterogeneous catalysis, i.e. surface reactions at the gas-solid interface, to reaction engineering, i.e. scaling relations and technical hurdles. In addition, the article introduces concepts and workflows that aim at providing guidance during the design of technological solutions for the efficient control of gaseous PFAS emissions.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC12070372 | PMC |
http://dx.doi.org/10.1002/anie.202424718 | DOI Listing |
Anaesthesia
September 2025
Department of Applied Health Sciences, School of Health Sciences, University of Birmingham, UK.
Introduction: Restoration of surgical capacity is essential to post-COVID-19 recovery. This study explored the use and safety of anaesthesia options for inguinal hernia surgery, a common tracer condition, to describe current global practice and highlight opportunities to build the capacity of health systems.
Methods: This is a secondary analysis of an international prospective cohort study of consecutive patients who underwent elective inguinal hernia surgery.
J Colloid Interface Sci
September 2025
Department of Global Smart City & School of Civil, Architectural Engineering, and Landscape Architecture, Sungkyunkwan University, Suwon 16419, Republic of Korea. Electronic address:
Platinum and nitrogen co-doped titanium dioxide (Pt/N-TiO, with 1 wt% Pt and an N/Ti molar ratio of 1) has been synthesized. This Pt/N co-doping strategy creates Schottky junctions, reduces the bandgap energy (3.25 to 2.
View Article and Find Full Text PDFEnviron Sci Technol
September 2025
State Key Joint Laboratory of Environment Simulation and Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.
The rapid growth of natural-gas vehicles (NGVs) necessitates robust catalysts for the simultaneous abatement of methane (CH), nitrogen oxides (NO), and carbon monoxide (CO) under fluctuating exhaust compositions. We reported a site-engineered MnGa@In-CHA OXZEO catalyst in which indium was confined within an SSZ-13 framework, and GaO and MnO phases were uniformly dispersed on its exterior. MnO markedly enhanced redox capacity, driving NO → NO oxidation and lowering the activation energy for C-H bond cleavage in CH, while GaO tuned the Brønsted acidity and mediated electron transfer among In, Mn, and Ga centers.
View Article and Find Full Text PDFAdv Mater
September 2025
Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore, 117585, Republic of Singapore.
Electrochemical CO reduction reaction (CORR) can enable the production of fuels and chemicals from CO emissions. Direct flue gas conversion can address the emissions from hard-to-abate sectors, including cement, steel, and power generation industries. Such integration with SCORR can also decarbonize the petrochemical industry and eliminate separation and purification steps.
View Article and Find Full Text PDFNat Commun
August 2025
Department of Mechanical Engineering, University of Alberta, Edmonton, AB, Canada.
Electrolytic hydrogen can support the decarbonization of the power sector. Achieving cost-effective power-to-gas-to-power (PGP) integration through targeted emissions pricing can accelerate the adoption of electrolytic hydrogen in greenhouse gas-intensive power sectors. This study develops a framework for assessing the economic viability of electrolytic hydrogen-based PGP systems in fossil fuel-dependent grids, while considering the competing objectives of the electricity system operator, a risk-averse investor, and the government.
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