Controllable Growth of Wafer-Scale TeSe Thin Films Based on Selenium Phase Change-Induced Strategy for Single-Pixel Imaging.

Recently, TeSe films have shown significant potential for infrared detection. However, the conventional deposition process of TeSe films typically requires a cooled substrate, which results in the formation of poorly crystallized materials. Achieving controlled synthesis of large-area TeSe films remains a major challenge. Herein, two-inch TeSe films is successfully prepared using a low-pressure chemical vapor deposition technique based on a selenium phase transition-induced strategy. The chemical compositions of TeSe (x ranging from 0 to 1) films can be precisely controlled by adjusting the molar ratio of Te and Se powders. The phase change of amorphous Se at elevated temperatures generates additional dangling bonds on its surface, which facilitates the incorporation of Te atoms into Se chains forming TeSe alloys. COMSOL simulations reveal that maintaining uniform concentration and temperature during the growth process is essential for the formation of TeSe films. Importantly, the TeSe film detector realizes high-performance near-infrared single-pixel imaging with a resolution of 128 × 128 pixels. This work has fabricated wafer-scale TeSe alloy thin films, which exhibit excellent properties, providing important experimental and theoretical support for exploring the applications in the fields of electronics, photonics, and optoelectronics.