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This study presents the synthesis of a green polymer-based nanocomposite by incorporating green CuO nanoparticles into polyaniline (PANI) for the adsorption of Pb (II) ions from contaminated water. The nanocomposite was extensively characterized using FTIR, XRD, BET, SEM-EDX, XPS, and Raman spectroscopy, both before and after Pb(II) adsorption. Optimization studies were performed to assess the effects of key parameters, including pH, adsorbent dosage, and initial ion concentration on the adsorption process. Adsorption isotherms and kinetic models were applied to analyze the experimental data, revealing that the Freundlich isotherm provided the best fit, with a high correlation coefficient (R²) and a (1/n) value less than 1, indicating favorable adsorption conditions. Furthermore, the Avrami and pseudo-first-order kinetic models demonstrated superior fitting compared to other models. The green nanocomposite exhibited outstanding adsorption capacity, highlighting its potential as a sustainable and efficient adsorbent for Pb(II) removal from wastewater.
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http://dx.doi.org/10.1038/s41598-024-81970-2 | DOI Listing |
Environ Monit Assess
September 2025
School of Chemical Engineering, Universiti Sains Malaysia, Engineering Campus, 14300, Nibong Tebal, Penang, Malaysia.
Ciprofloxacin (CIP), a widely used fluoroquinolone antibiotic, has become a significant contaminant in aquatic environments due to its extensive use and incomplete metabolism. This review comprehensively analyses CIP pollution, including its sources, environmental and health impacts, and removal strategies. Chemical methods such as advanced oxidation processes and physical techniques like adsorption are evaluated for their efficiency in CIP removal.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
September 2025
Faculty of Environment and Resource Studies, Mahidol University, Salaya, Phutthamonthon, Nakhon Pathom, 73170, Thailand.
Soil washing with surfactants is a promising technique for remediating petroleum hydrocarbon-contaminated soils. This study evaluates a biosurfactant extracted from Eichhornia crassipes (water hyacinth), an abundant aquatic weed in Thailand, using ultrasound-assisted extraction for diesel-contaminated soil remediation. The biosurfactant extract (Extract WH) was characterized for its surface tension reduction, critical micelle concentration (CMC), emulsification capacity with diesel, and phytotoxicity.
View Article and Find Full Text PDFArch Environ Contam Toxicol
September 2025
Department of Marine Biology, Texas A&M University at Galveston, 200 Seawolf Parkway, Galveston, TX, 77553, USA.
Karst water bodies are vital groundwater resources particularly vulnerable to pollution. Protecting their water quality requires documenting contaminants traditionally associated with anthropogenic activities (metals, nutrients, and fecal indicator bacteria) as well as emerging contaminants, such as antibiotic-resistant organisms (AROs) and perfluoroalkyl substances (PFAS). This study detected contaminants in karst-associated water bodies on the Yucatán Peninsula, including 10 sinkholes (cenotes) and one submarine groundwater discharge (SGD) site.
View Article and Find Full Text PDFEnviron Res
September 2025
Thrust of Sustainable Energy and Environment, Function Hub, The Hong Kong University of Science and Technology (Guangzhou), Guangzhou 510000, China. Electronic address:
China's aluminum-products industry, a large-scale consumer of industrial paints, is a potentially significant source of full-volatility organic compounds (F-VOCs). However, the emission characteristics of F-VOCs, including VOCs, intermediate-, semi-, and low-volatility organic compounds (I/S/LVOCs), and their role in ozone formation potentials (OFP), and secondary organic aerosol formation potentials (SOAP) remain unclear. In this study, we collected in-field samples from three industrial paints (solvent-based, water-based and powder paints) at spraying and drying processes, and treatment devices to analyze the emission characteristics of F-VOCs, OFP, SOAP.
View Article and Find Full Text PDFEnviron Res
September 2025
State Key Laboratory for Ecological Security of Regions and Cities, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China. Electronic address:
Recent interest in amendments derived from industrial by-products has highlighted their potential for both resource recycling and heavy metal remediation. Phosphate tailings (PT), primarily dolomite-based solid waste with low utilization rates, offer a promising yet underexplored solution. This study pioneers the thermal modification of PT into a novel amendment, thermally modified phosphate tailings (TPT), to assess its adsorption performance, underlying mechanisms, and effectiveness in immobilizing heavy metals in soils.
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