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High spin polarization and low resistivity of FeO at room temperature have been an appealing topic in spintronics with various promising applications. High-quality FeO thin films are a must to achieve the goals. In this report, FeO films on different substrates (SiO/Si(100), MgO(100), and MgO/Ta/SiO/Si(100)) were fabricated at room temperature with radio-frequency (RF) sputtering and annealed at 450 °C for 2 h. The morphological, structural, and magnetic properties of the deposited samples were characterized with atomic force microscopy, X-ray diffractometry, and vibrating sample magnetometry. The polycrystalline FeO film grown on MgO/Ta/SiO/Si(100) presented very interesting morphology and structure characteristics. More importantly, changes in grain size and structure due to the effect of the MgO/Ta buffering layers have a strong impact on saturation magnetization and coercivity of FeO thin films compared to cases of no or just a single buffering layer.
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http://dx.doi.org/10.3762/bjnano.15.101 | DOI Listing |
ACS Nano
August 2025
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China.
Room-temperature multiferroic BiFeO (BFO) is a promising candidate for next-generation memory and spintronic devices, but its synthesis is hindered by metastability and complex phase evolution pathways. Achieving atomic-scale control over these pathways is critical for unlocking BFO's functional potential. Here, we integrate atomic-resolution scanning transmission electron microscopy, energy-dispersive X-ray spectroscopy and density functional theory to dissect the BFO formation mechanism using annealed Bi/Fe thin-film model systems.
View Article and Find Full Text PDFAdv Sci (Weinh)
August 2025
Department of Physics, Korea Advanced Institute of Science and Technology, Daejeon, 34141, Republic of Korea.
Controlling the non-stoichiometry is an effective way to tune physicochemical properties of functional oxides and explore novel physical phenomena in complex oxides. Therefore, quantitative control of oxygen non-stoichiometry in perovskite oxides plays an important role in understanding the mechanism of topotactic phase transition and improving the applicability of electrochemical devices. Here, an electrochemical titration cell is fabricated to control the oxygen non-stoichiometry of a BiCaFeO thin film grown on yttria-stabilized zirconia substrate.
View Article and Find Full Text PDFJ Mater Chem A Mater
July 2025
Institute of Chemical Technologies and Analytics, Research Group for Electrochemical Energy Conversion TU Wien Austria
The (electro)chemical properties of electrode materials in solid oxide cells or oxide-based redox catalysts are determined by the surface chemistry of these materials under operation conditions. Surface point defect concentrations strongly depend on the oxygen stoichiometry in the bulk and the gas phase's chemical composition (, oxygen activity). However, many chemically sensitive surface analysis techniques rely on UHV conditions, leading to a two-fold deviation from surfaces under operational conditions.
View Article and Find Full Text PDFSci Rep
July 2025
Data-Driven Inorganic Materials Group, Center for Basic Research on Materials, National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki, 305-0047, Japan.
Thermoelectric (TE) materials offer a promising pathway toward achieving carbon neutrality by converting waste heat into electricity. The enhancement of their figure-of-merit (zT) depends on optimizing the composition of materials and nanostructures, reducing the thermal conductivity, and increasing the power factor. CuSe, a superionic material, achieves a zT of 0.
View Article and Find Full Text PDFDespite the appeal of flawless order, semiconductor technology has demonstrated that implanting inhomogeneities into single-crystalline materials is pivotal for modern electronics. However, the influence of the local arrangement of chemical inhomogeneities on the material's functionalities is underexplored. In this work, we control the distribution of chemical inhomogeneities in La-substituted ferroelectric BiFeO thin films.
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