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Sandy conglomerate reservoirs have become an important replacement area for unconventional energy to increase reserves and production. The polymer/surfactant composite control flooding system can effectively alleviate the water flooding front breakthrough caused by the interlayer or plane heterogeneity of the sand conglomerate reservoir and is an effective production method to reduce the water cutoff of the well and increase the oil recovery. In the process of controlling the oil displacement process of the system, the chromatographic separation effect was found due to the different viscosities of each component and the adsorption difference between the components and the rock, which weakened the development effect of the reservoir. It is necessary to study the adsorption law of each component of the complex controlled displacement system along the injection-production channel in the sand conglomerate reservoir. In this study, the microstructure and mineral composition of sandy conglomerates were determined by scanning electron microscopy and X-ray diffraction tests. The main particle size distribution was counted through a rock particle sieving experiment. A new characterization method called the large-size core physical model was used. The composite control system of sulfonate and betaine was used as the surfactant component, and the adsorption degree of each component in the displacement process was analyzed. The experimental results showed that the mass fraction of the sandy conglomerate increased with the decrease in particle size. The particles with a size of less than 0.08 mm account for a relatively high proportion, with a mass fraction of 60%. The content of brittle minerals, such as quartz and feldspar, in the glutenite was relatively high, and micrometer-sized pores and fractures were developed. The main factors affecting the viscosity of the composite system were the concentration and molecular weight of the polymer. The increase of injection volume of the flooding system is conducive to the maintenance of ultralow interfacial tension migration to the deep core. In the displacement process, when the polymer molecular chain was cut to a certain extent, the effect of throat shear was also slowed due to the short molecular chain. However, the shortened polymer molecules were more easily adsorbed on the surface of rock particles and the adsorption rate increased. The adsorption capacity of each component gradually decreased with the increase of the injection volume and injection concentration. The relative content of the composite control system and crude oil affects the type of emulsion, which undergoes a corresponding transformation during the driving process from a water-in-oil emulsion to an oil-in-water one. The research results of this paper enrich the mechanism of enhancing oil recovery of sand conglomerate reservoirs by polymer-surfactant composite regulation technology.
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http://dx.doi.org/10.1021/acsomega.4c04906 | DOI Listing |
ACS Nano
September 2025
Eastern Institute for Advanced Study, Eastern Institute of Technology, Ningbo, Zhejiang 315200, P. R. China.
Ni-Fe (oxy)hydroxides are among the most active oxygen evolution reaction (OER) catalysts in alkaline media. However, achieving precise control over local asymmetric Fe-O-Ni active sites in Ni-Fe oxyhydroxides for key oxygenated intermediates' adsorption steric configuration regulation of the OER is still challenging. Herein, we report a two-step dealloying strategy to fabricate asymmetric Fe-O-Ni pair sites in the shell of NiOOH@FeOOH/NiOOH heterostructures from NiFe Prussian blue analogue (PBA) nanocubes, involving anion exchange and structure reconstruction.
View Article and Find Full Text PDFJ Agric Food Chem
September 2025
Department of Food Science and Engineering, Ningbo University, Ningbo 315211, P.R. China.
Sleep deprivation (SD) is a major contributor to cognitive impairment, often accompanied by central neuroinflammation and gut microbiota dysbiosis. The tryptophan (TRP) pathway, activated via indoleamine 2,3-dioxygenase (IDO), serves as a critical link between immune activation and neuronal damage. Umbelliferone (UMB), a naturally occurring coumarin compound, possesses anti-inflammatory, antioxidant, and microbiota-modulating properties.
View Article and Find Full Text PDFRetina
September 2025
School of Mathematical and Computational Sciences, University of Prince Edward Island, Charlottetown, Canada.
Purpose: Systemically administered anti-cancer VEGF inhibiting therapies can cause severe kidney injury. Intravitreal aflibercept has a greater impact on renal VEGF levels than ranibizumab. We compared the risk of kidney injury among patients receiving intravitreal aflibercept vs.
View Article and Find Full Text PDFHepatology
September 2025
Department of Gastroenterology and Hepatology, UT Southwestern, Dallas, TX.
Background: The clinical course and outcomes of alcohol-associated hepatitis (AH) remain poorly understood. Major adverse liver outcomes (MALO) do not capture the added risk of return to drinking (RTD). We examined the natural history of AH and developed a composite endpoint using a contemporary observational cohort of AH.
View Article and Find Full Text PDFPLoS One
September 2025
The George Institute for Global Health, Imperial College London, London, United Kingdom.
Background: Tobacco use remains a major public health challenge in sub-Saharan Africa, with significant gendered dimensions. Place of residence is an important determinant, as rural and urban contexts shape exposure, access, and consumption patterns. This study investigates rural-urban disparities in tobacco use among women in sub-Saharan Africa, with a focus on quantifying the relative contributions of socioeconomic factors.
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