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This review explores the expanding role of electrochemical sensors across diverse domains such as environmental monitoring, medical diagnostics, and food quality assurance. In recent years, iron-based electrocatalysts have emerged as promising candidates for enhancing sensor performance. Notable for their non-toxicity, abundance, catalytic activity, and cost-effectiveness, these materials offer significant advantages. However, further investigation is needed to fully understand how iron-based materials' physical, chemical, and electrical properties influence their catalytic performance in sensor applications. It explores the overview of electrochemical sensor technology, examines the impact of iron-based materials and their characteristics on catalytic activity, and investigates various iron-based materials, their advantages, functionalization, and modification techniques. Additionally, the review investigates the application of iron-based electrode material composites in electrochemical sensors for real sample detections. Ultimately, continued research and development in this area promise to unlock new avenues for using iron-based electrode materials in sensor applications.
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http://dx.doi.org/10.1016/j.scitotenv.2024.176128 | DOI Listing |
Adv Mater
August 2025
Division of Energy Storage, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
Halide cathode active materials (CAMs) with high ionic conductivities have attracted significant attention. However, their capacity and energy density are limited by the large molar weight of the Li⁺ transport-dependent MCl anionic framework. In this study, a low-cost amorphous iron-based oxyhalide LFFOC-0.
View Article and Find Full Text PDFJ Colloid Interface Sci
August 2025
School of Chemistry, Beihang University, Beijing 100191, PR China. Electronic address:
New-type and high-quality cathodes are of immense importance for the development of aqueous zinc-ion batteries (AZIBs). Herein, a core-shell structural iron-based metal organic framework (MIL-88) derived cathode (ZnFeO/FeO/C@NC/MoTiCT) with admirable specific capacity, rate performance, and cycling stability has been firstly designed and prepared. The in-situ adulterated Zn and loaded MoTiCT MXene could effectively modulate the electron distribution, facilitating the electron transfer from Fe and Zn to O atoms, which dramatically decrease the adsorption Gibbs energy for charge carriers and improve the electrical conductivity, leading to fast electrochemical kinetics.
View Article and Find Full Text PDFJ Colloid Interface Sci
August 2025
Department of Chemistry, School of Chemistry and Chemical Engineering, Key Laboratory of Surface & Interface Science of Polymer Materials of Zhejiang Province, Zhejiang Sci-Tech University, Hangzhou 310018, China. Electronic address:
Developing iron-based nanozymes with highly active sites and elucidating their catalytic mechanisms hold great promise for advancing applications in food safety, environmental monitoring and clinical medicine. Herein, vanadium (V)-doped FeO (V-FeO) nanozymes with peroxidase (POD)-mimetic activity were fabricated using a post-doping method and employed to construct a colorimetric/electrochemical dual-mode sensor for quantitative analysis of nitrite (NO). Experimental and density functional theory data show that the dopant of V into the structure of V-FeO nanozymes can enhance their POD-mimetic activity due to the increased oxygen vacancies and the improved adsorption ability for HO.
View Article and Find Full Text PDFLangmuir
September 2025
Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, College of Chemistry and Chemical Engineering, Hubei Normal University, Huangshi 435002, People's Republic of China.
Aqueous rechargeable Ni-Fe batteries exhibit considerable potential for use in large-scale energy storage systems due to their stable operating voltage, inherent safety, low cost, and high power density. Herein, a core-shell composite was designed for anode applications in which the FeCO@FeCO polyhedron and the polythiophene (PTh) layer serve as the core and shell, respectively. Owing to its core-shell structure, multicomponent synergistic effect, rough surface morphology, and enhanced electrical conductivity, the as-fabricated binder-free FeCO@FeCO-PTh electrode delivers excellent electrochemical performance, including high specific capacities (10.
View Article and Find Full Text PDFAdv Mater
August 2025
College of Chemistry, Zhengzhou University, Zhengzhou, 450001, China.
Na Super Ionic CONductor (NASICON)-type iron-based phosphate cathode has attained extensive research interest due to its green, low cost, and superior rate capability for sodium-ion batteries (SIBs). However, owing to strong Fe─O covalent character in the NASICON frameworks, the low Fe/Fe redox potential (<2.5 V vs Na/Na) has led to an undesirable energy density of phosphate cathode.
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