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Superconductivity involving finite-momentum pairing can lead to spatial-gap and pair-density modulations, as well as Bogoliubov Fermi states within the superconducting gap. However, the experimental realization of their intertwined relations has been challenging. Here we detect chiral kagome superconductivity modulations with residual Fermi arcs in KVSb and CsVSb using normal and Josephson scanning tunnelling microscopy down to 30 millikelvin with a resolved electronic energy difference at the microelectronvolt level. We observe a U-shaped superconducting gap with flat residual in-gap states. This gap shows chiral 2a × 2a spatial modulations with magnetic-field-tunable chirality, which align with the chiral 2a × 2a pair-density modulations observed through Josephson tunnelling. These findings demonstrate a chiral pair density wave (PDW) that breaks time-reversal symmetry. Quasiparticle interference imaging of the in-gap zero-energy states reveals segmented arcs, with high-temperature data linking them to parts of the reconstructed vanadium d-orbital states within the charge order. The detected residual Fermi arcs can be explained by the partial suppression of these d-orbital states through an interorbital 2a × 2a PDW and thus serve as candidate Bogoliubov Fermi states. In addition, we differentiate the observed PDW order from impurity-induced gap modulations. Our observations not only uncover a chiral PDW order with orbital selectivity but also show the fundamental space-momentum correspondence inherent in finite-momentum-paired superconductivity.
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http://dx.doi.org/10.1038/s41586-024-07798-y | DOI Listing |
ACS Appl Mater Interfaces
April 2025
National Key Laboratory of Advanced Polymer Materials, Polymer Research Institute, Sichuan University, Chengdu 610065, China.
Nitrogen and sulfur co-doped graphene composite aerogel microspheres containing pyrolyzed carbon (NS-GAMs@C) are prepared by pressure-spraying the graphene oxide (GO) dispersion with water-soluble phenolic resin and thiourea, followed by freeze shaping, freeze-drying, and high-temperature carbonization. The resulting NS-GAMs@C possesses interconnected porous structures with large surface areas and high doping levels of N/S elements. Furthermore, the platinum nanoparticles (Pt NPs) are grown onto the NS-GAMs@C via a solvothermal reduction reaction to obtain the Pt/NS-GAMs@C microspheres with an average particle size of ∼32.
View Article and Find Full Text PDFJ Phys Condens Matter
March 2025
Materials Physics Research Institute, School of Physics, University of the Witwatersrand, Johannesburg 2000, Gauteng, South Africa.
We report on the observation of a flat band situated at the Fermi levelEFalong with the structural, electrical transport, and magnetic properties of BaCoPthat crystallizes in the ThCrSi-type body-center tetragonal structure. This compound has the largest inter-layer pnictide () distancedPn-Pnas well as the largestc/aratio among all the knownCo2Pn2(= alkaline earth metal) compounds, whereandare the tetragonal lattice parameters. Hence, the magnetic and electronic properties of this compound are expected to have a quasi-two-dimensional character.
View Article and Find Full Text PDFNat Commun
January 2025
Anhui Key Laboratory of Magnetic Functional Materials and Devices, Institutes of Physical Science and Information Technology, Anhui University, Hefei, Anhui, China.
Thermal conductivity and electrical resistivity at ultralow temperatures and high magnetic fields are studied in the topological compensated semimetals TaAs, NbAs, and NdSb. A striking phenomenon is observed where the thermal conductivity shows a T scaling at very low temperatures, while the resistivity shows a T-independent residual term. This indicates a strong violation of the Wiedemann-Franz (WF) law, since the field dependence of κ shows that the low-temperature thermal conductivity is dominated by electronic transport.
View Article and Find Full Text PDFPhys Rev Lett
October 2024
Department of Advanced Materials Science, University of Tokyo, Kashiwa, Chiba 277-8561, Japan.
The observation of time-reversal symmetry breaking and large residual density of states in tetragonal FeSe_{1-x}S_{x} suggests a novel type of ultranodal superconducting state with Bogoliubov Fermi surfaces (BFSs). Although such BFSs in centrosymmetric superconductors are expected to be topologically protected, the impurity effect of this exotic superconducting state remains elusive experimentally. Here, we investigate the impact of controlled defects introduced by electron irradiation on the superconducting state of tetragonal FeSe_{1-x}S_{x} (0.
View Article and Find Full Text PDFNature
August 2024
Department of Physics, Southern University of Science and Technology, Shenzhen, China.
Superconductivity involving finite-momentum pairing can lead to spatial-gap and pair-density modulations, as well as Bogoliubov Fermi states within the superconducting gap. However, the experimental realization of their intertwined relations has been challenging. Here we detect chiral kagome superconductivity modulations with residual Fermi arcs in KVSb and CsVSb using normal and Josephson scanning tunnelling microscopy down to 30 millikelvin with a resolved electronic energy difference at the microelectronvolt level.
View Article and Find Full Text PDF