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Chiral optical beams that carry orbital angular momentum (OAM) have a broad range of applications such as optical tweezers, chiral microstructure fabrication, and optical communications. However, some chiral optical beams have inhomogeneous intensity distribution that limits the application in these fields. In this Letter, two different types of chiral optical fields with uniform intensity and arbitrary length were proposed based on the amplitude encoding method and multifocal synthesis. The intensity distribution of the chiral optical fields is determined by the distance between the focal points that can greatly extend the modulation length of the chiral optical field. Moreover, since each focal point contains modulable amplitude and phase, an arbitrary interception of the optical field can be realized by selectively retaining a part of the focal points. By partitioning the chiral optical field and assigning different topological charges, the OAM space-division multiplexing and independent tunability of the topological charges can be realized. In addition, the composite multi-petal vortex array formed by combining two different chiral optical fields can greatly enhance the information capacity of the optical communications and may have potential applications in fields such as particle manipulation.
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http://dx.doi.org/10.1364/OL.528531 | DOI Listing |
J Am Chem Soc
September 2025
Dipartimento di Biotecnologie, Chimica e Farmacia, Università di Siena, via A. Moro 2, 53100 Siena, Italy.
Molecules with an inverted singlet-triplet gap (Δ = - < 0) hold potential for optoelectronic applications as OLEDs and photocatalysis. Despite growing interest, no single-molecule emission from a chiral dye with an inverted gap has been reported, and only one case has shown such emission from supramolecular aggregates. Here, we present the first circularly polarized light emission (CPL) from a chiral molecule exhibiting an inverted singlet-triplet gap.
View Article and Find Full Text PDFPhys Rev Lett
August 2025
Weizmann Institute of Science, Department of Physics of Complex Systems, Rehovot 761001, Israel.
The coupling of lasers plays an important role in a variety of research activities, from generating high-power lasers to investigating out-of-equilibrium coupled systems. This Letter presents our investigations of Hermitian coupling in arrays of lasers, where it is possible to control both the amplitude and phase of the coupling and generate artificial gauge fields. The Hermitian coupling is demonstrated in three laser array geometries: a square array of 100 lasers with controlled laser coupling for obtaining continuous control over the phase-locked state, a triangular array of 130 lasers with controlled chirality of the lasers, and a ring array of eight lasers with a controlled topological charge.
View Article and Find Full Text PDFBeilstein J Org Chem
September 2025
State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China.
Both chiral bisoxazolines and bisimidazolines are efficient chiral ligands in metal-catalyzed asymmetric organic transformations. Chiral cyclohexane-linked bisimidazolines were prepared from optically active cyclohexane-1,2-dicarboxylic acid and 1,2-diphenylethane-1,2-diamines via the monosulfonylation of 1,2-diphenylethane-1,2-diamines, condensation of -sulfonylated 1,2-diphenylethane-1,2-diamines and cyclohexane-1,2-dicarboxylic acid, and the final cyclization with the in situ generated Hendrickson reagent.
View Article and Find Full Text PDFChirality
September 2025
Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Pisa, Italy.
A recent publication by Kopec et al., "The effect of enantiomers of thalidomide on colon cells-Raman spectroscopy studies", reported to "demonstrate that Raman spectroscopy reveals distinct spectral differences between the enantiomers of thalidomide" and provided both experimental and computational evidence. However, the theory of Raman spectroscopy inherently establishes that two enantiomers must exhibit identical Raman frequencies and intensities.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
State Key Laboratory of Chemical Resource Engineering, Beijing 100029, China.
Circularly polarized luminescence (CPL) has emerged as a critical technology for anticounterfeiting and optical display applications due to its unique chiroptical properties. We report a multicolor CPL-emitting elastomeric film (P37/PSK@SiO-PDMS) that synergistically combines chiral helical polyacetylene (P37) and a surface-engineered perovskite (PSK@SiO) through hydrogen-bond-directed assembly. Confinement within the PDMS matrix drives P37 to self-assemble into a chiral supramolecular structure through hydrogen bonding, inducing a chiroptical inversion.
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