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The study investigated the effects of temperature and centrifugation time on the efficacy of removing uncured resin from 3D-printed clear aligners. Using a photo-polymerizable polyurethane resin (Tera Harz TC-85, Graphy Inc., Seoul, Korea), aligners were printed and subjected to cleaning processes using isopropyl alcohol (IPA) or centrifugation (g-force 27.95g) at room temperature (RT, 23 °C) and high temperature (HT, 55 °C) for 2, 4, and 6 min. The control group received no treatment (NT). Cleaning efficiency was assessed through rheological analysis, weight measurement, transparency evaluation, SEM imaging, 3D geometry evaluation, stress relaxation, and cell viability tests. Results showed increased temperature and longer centrifugation times significantly reduced aligner viscosity, weight (P < 0.05), and transmittance. IPA-cleaned aligners exhibited significantly lower transparency and rougher surfaces in SEM images. All groups met ISO biocompatibility standards in cytotoxicity tests. The NT group had higher root mean square (RMS) values, indicating greater deviation from the original design. Stress relaxation tests revealed over 95% recovery in all groups after 60 min. The findings suggest that a 2-min HT centrifugation process effectively removes uncured resin without significantly impacting the aligners' physical and optical properties, making it a clinically viable option.
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http://dx.doi.org/10.1038/s41598-024-66150-6 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
The Steve Sanghi College of Engineering, Mechanical Engineering, Northern Arizona University, Flagstaff, Arizona 86011, United States.
This study investigates the HO and CO sorption behavior of two chemically distinct polystyrene-divinylbenzene-based ion exchange sorbents: a primary amine and a permanently charged strong base quaternary ammonium (QA) group with (bi)carbonate counter anions. We compare their distinct interactions with HO and CO through simultaneous thermal gravimetric, calorimetric, gas analysis, and molecular modeling approaches to evaluate their performance for dilute CO separations like direct air capture. Thermal and hybrid (heat + low-temperature hydration) desorption experiments demonstrate that the QA-based sorbent binds both water and CO more strongly than the amine counterparts but undergoes degradation at moderate temperatures, limiting its compatibility with thermal swing regeneration.
View Article and Find Full Text PDFAnnu Rev Entomol
September 2025
5Department of Entomology, University of Georgia, Athens, Georgia, USA; email:
Wetlands and their aquatic arthropods are threatened by climate change (temperature, precipitation). In this review, we first synthesize the literature on environmental controls on wetland arthropods (hydroperiod, temperature, dissolved oxygen) and then assess how these controls operate across freshwater wetlands from different global biomes (tropical/subtropical, temperate, high latitude/altitude, and dry climates) and how changes in climates alter arthropod fauna with consequent modifications to wetland ecosystem functions (decomposition, food web dynamics). We also describe ways to develop bioassessment of climate change impacts on wetlands.
View Article and Find Full Text PDFLangmuir
September 2025
State Key Laboratory of Solid Waste Reuse for Building Materials, Beijing Building Materials Academy of Sciences Research, Beijing 100041, China.
This article is based on the research background of an early performance of shotcrete under low-temperature environments. Silica fume (SF) (silicon powder) and nano-CSH are used to improve the effect of the low-temperature environment on the performance of alkali-free (AF) liquid accelerators and early strength of shotcrete. The results show that the 10% SF and 3% nano-CSH composite admixture significantly enhances AF accelerators' performance at 5 °C, reducing initial and final setting times to 3.
View Article and Find Full Text PDFJ Am Soc Mass Spectrom
September 2025
Chemistry Department, Indiana University, 800 E Kirkwood Ave, Bloomington, Indiana 47405.
In charge detection mass spectrometry (CD-MS) ions are trapped in an electrostatic linear ion trap (ELIT) where they oscillate back and forth through a conducting cylinder. The oscillating ions induce a periodic charge separation that is detected by a charge sensitive amplifier (CSA) connected to the cylinder. The resulting time domain signal is analyzed using short-time Fourier transforms to give the mass-to-charge ratio and charge for each ion, which are then multiplied to give the mass.
View Article and Find Full Text PDFJ Agric Food Chem
September 2025
Department of Biotechnology, Graduate School of Engineering, The University of Osaka, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
During brewing processes, proteins such as lipid transfer protein 1 (LTP1) are exposed to high temperatures, which later affects the beer foam properties. To develop high-quality beer, it is therefore essential to understand the protein chemical modifications and structural alternations induced by the high temperatures and their impact on beer foam. This study characterizes heat-induced chemical modifications and changes in the molecular size distribution and structure of LTP1 and its lipid-bound isoform, LTP1b, using size-exclusion chromatography and reverse-phase chromatography/mass spectrometry.
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