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This study investigates the effect of a high-temperature annealing process on the characteristics and performance of a memristor based on a Ag/GaO/Pt structure. Through X-ray diffraction analysis, successful phase conversion from amorphous GaO to β-GaO is confirmed, attributed to an increase in grain size and recrystallization induced by annealing. X-ray photoelectron spectroscopy analysis revealed a higher oxygen vacancy in annealed GaO thin films, which is crucial for conductive filament formation and charge transport in memristors. Films with abundant oxygen vacancies exhibit decreased set voltages and increased capacitance in a low-resistive state, enabling easy capacitance control depending on channel presence. In addition, an excellent memory device with a high on/off ratio can be implemented due to the reduction of leakage current due to recrystallization. Therefore, it is possible to manufacture a thin film suitable for a memristor by increasing the oxygen vacancy in the GaO film while improving the overall crystallinity through the annealing process. This study highlights the significance of annealing in modulating capacitance and high-resistive/low-resistive state properties of GaO memristors, contributing to optimizing device design and performance. This study underscores the significance of high-temperature annealing in improving the channel-switching characteristics of GaO-based memristors, which is crucial for the development of low-power, high-efficiency memory device.
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http://dx.doi.org/10.3390/ma17112727 | DOI Listing |
Langmuir
September 2025
College of Applied Science and Technology, Hainan University, Haikou 570228, China.
This study systematically investigates the role of nitrogen annealing in enhancing the structural and electrochemical properties of ZnNiO/NF composite anode materials synthesized via hydrothermal methods. By comparing air-annealed and nitrogen-annealed (400 and 600 °C) samples, it is demonstrated that nitrogen annealing at 400 °C induces the densely stacked nanosheet morphology with optimized lattice regularity, which can significantly improve the charge transport kinetics and the interfacial stability. Electrochemical evaluations reveal an outstanding initial discharge capacity of 1873.
View Article and Find Full Text PDFChem Sci
August 2025
State Key Laboratory of Antiviral Drugs, Pingyuan Laboratory, NMPA Key Laboratory for Research and Evaluation of Innovative Drug, School of Chemistry and Chemical Engineering, Henan Normal University 46 Jianshe Road Xinxiang 453007 China +86
The construction of polymer-based photoactivated room-temperature phosphorescence systems remains a prominent research focus, yet the development of ultrafast activated systems under ambient conditions continues to pose a challenge. In this study, cyclized phenothiazine derivatives bearing diverse substituents are synthesized and incorporated into an amorphous polyvinyl alcohol (PVA) matrix, resulting in significantly enhanced dynamic photoactivation characteristics compared with those of their pristine monomeric counterparts. Under ambient conditions and 2 s irradiation, the lifetime and quantum yield of C[4]PTZ-OH@PVA increase by factors of 1.
View Article and Find Full Text PDFRSC Adv
August 2025
University of Coimbra, CFisUC, Physics Department Rua Larga P-3004-516 Coimbra Portugal
Nanoscale materials are attracting a great deal of attention due to their exceptional properties, making them indispensable for many advanced applications. Among these materials, spinel ferrites stand out for their potential applications in electronic, optoelectronic, energy storage and other devices. This is why the development of a synthesis process combined with rigorous optimization of annealing conditions is provided to be an essential approach to control nanoparticle formation and fine-tuning their structural, morphological and functional characteristics.
View Article and Find Full Text PDFWater Res
August 2025
School of Materials and Energy, University of Electronic Science and Technology of China, 610054 Chengdu, China; Sichuan Province Engineering Technology Research Center of Novel CN Polymeric Materials, Chengdu, China. Electronic address:
The scalable fabrication of high performance dyes desalination loose nanofiltration (LNF) membrane through facile thermal annealing remains challenging due to the susceptible pore collapse. Herein, we have developed a metal ion mediated sub-Tg thermal crosslinking protocol, which can convert the phase inverted reactive polymeric ultrafiltration substrate into LNF membrane showing high permselectivity as well as resistance to both extremely acid and alkaline solution. The original ultrafiltration substrate was composed of scalable-produced reactive polyarylene ether amidoxime (PEA) that was pre-crosslinked with ferric ions.
View Article and Find Full Text PDFACS Macro Lett
September 2025
State Key Laboratory of Advanced Polymer Materials, Polymer Research Institute of Sichuan University, Chengdu 610065, China.
Typically, specific amide nucleating agents (NAs) that can form nanofibrous networks by self-assembly are vital to achieve poly(l-lactic acid) (PLA) with good heat resistance and transparency. However, the long time required for self-assembly during rapid cooling results in a narrow crystallization window for induced PLA, thus requiring a combination of high annealing temperature and a long annealing time. Herein, a synergistic nucleation strategy was introduced to address this challenge, i.
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