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Article Abstract
Synthesis, characterization, electronic structure, and redox reactions of a mononuclear {FeNO} complex with a very high N-O stretching frequency in solution are presented. Nitrosylation of [(L)Fe(DMF)] () (L = tris((1-methyl-4,5-diphenyl-1H-imidazol-2-yl)methyl)amine) produced a five-coordinate {FeNO} complex, [(L)Fe(NO)] (). While complex could accommodate an additional water molecule to generate a six-coordinate {FeNO} complex, [(L)Fe(NO)(HO)] (), the coordinated HO in dissociates to generate in solution. The molecular structure of features a nearly linear Fe-N-O unit with an Fe-N distance of 1.744(4) Å, N-O distance of 1.162(5) Å, and
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http://dx.doi.org/10.1021/acs.inorgchem.3c03274 DOI Listing Publication Analysis
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