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Porous composite battery electrode performance is influenced by a large number of manufacturing decisions. While it is common to evaluate only finished electrodes when making process adjustments, one must then make inferences about the fabrication process dynamics from static results, which makes process optimization very costly and time-consuming. To get information about the dynamics of the manufacturing processes of these composites, we have built a miniature coating and drying apparatus capable of fabricating lab-scale electrode laminates while operating within an X-ray beamline hutch. Using this tool, we have collected the first radiography image sequences of lab-scale battery electrode coatings in profile, taken throughout drying processes conducted under industrially relevant conditions. To assist with interpretation of these image sequences, we developed an automated image analysis program. Here, we discuss our observations of battery electrode slurry samples, including stratification and long-term fluid flow, and their relevance to composite electrode manufacturing.
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http://dx.doi.org/10.1021/acsaem.4c00402 | DOI Listing |
Beilstein J Nanotechnol
September 2025
B. I. Stepanov Institute of Physics, National Academy of Sciences of Belarus, 220072 Minsk, Belarus.
In this study, silicon nanoparticles (NPs) were produced by pulsed laser ablation in a liquid, aiming to investigate the influence of a laser beam profile on the properties of the resultant NPs. Morphology, inner structure, and phase composition of the formed NPs were characterized by means of ultraviolet-visible spectroscopy, high-resolution transmission electron microscopy, and Raman and photoluminescence spectroscopies, and the correlation of the NP properties with the laser beam profile was studied. Three different beam profiles were selected, namely, a Bessel beam produced using an axicon, an annular profile formed using a combination of an axicon and a converging lens, and a Gaussian beam focused on the surface of a Si target using the same converging lens.
View Article and Find Full Text PDFNatl Sci Rev
September 2025
College of Chemistry, Huazhong Agricultural University, Wuhan 430070, China.
The stress distribution in Li metal strongly affects the interfacial Li-ion diffusion, thereby influencing the morphology of plated Li and the performance of the battery. Here, we report a mechano-electrochemical coupling strategy that utilizes an arched structured carbon aerogel to achieve stable Li-plating/stripping electrochemistry. The arch-structured carbon aerogel can actively regulate stress distributions in response to the compressive stresses induced by Li deposition, generating the transition of stress from compressive on the convex surface to tensile on the concave surface, which can effectively promote the Li-migration kinetics and thus suppress the non-uniform deposition of Li.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2025
Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074, China.
Ether-based electrolytes are widely acknowledged for their potential to form stable solid electrolyte interfaces (SEIs) for stable anode performance. However, conventional ether-based electrolytes have shown a tendency for cation-solvent co-intercalation phenomena on graphite electrodes, resulting in lower capacity and higher voltage platforms compared to those of neat cation insertion in ester-based electrolytes. In response, we propose the development of weakly solvating ether solvents to weaken the interaction between cations and solvents, thereby suppressing co-intercalation behavior.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
School of Integrated Circuits, State Key Laboratory of New Textile Materials and Advanced Processing, Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), Huazhong University of Science and Technology, Wuhan, 430074, China.
Low-temperature rechargeable batteries face great challenges due to the sluggish reaction kinetics. Redox covalent organic frameworks (COFs) with porous structures provide a viable solution to accelerate the ionic diffusion and reaction kinetics at low temperatures. However, the applications of COFs in low-temperature batteries are still at their infancy stage.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an 710049, China.
Economically viable and biologically compatible amino acids demonstrate significant potential as electrolyte microstructure modifiers in aqueous zinc-ion batteries (AZIBs). Compared to polar amino acids, nonpolar amino acids simultaneously own zincophilicity and hydrophobicity, showing great potential in the industrial application of AZIBs. However, nonpolar amino acids have been comparatively understudied in existing research investigations.
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