Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
The hydrolysis of hydrides, represented by MgH, delivers substantial capacity and presents an appealing prospect for an on-site hydrogen supply. However, the sluggish hydrolysis kinetics and low hydrogen yield of MgH caused by the formation of a passivation Mg(OH) layer hinder its practical application. Herein, we present a dual strategy encompassing microstructural design and compounding, leading to the successful synthesis of a core-shell-like nanostructured MgH@Mg(BH) composite, which demonstrates excellent hydrolysis performance. Specifically, the optimal composite with a low of 9.05 kJ mol releases 2027.7 mL g H in 60 min, and its hydrolysis rate escalates to 1356.7 mL g min H during the first minute at room temperature. The nanocoating Mg(BH) plays a key role in enhancing the hydrolysis kinetics through the release of heat and the formation of local concentration of Mg field after its hydrolysis. This work offers an innovative concept for the design of hydrolysis materials.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acs.nanolett.4c00115 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Incorporation of madımak (Polygonum cognatum Meissn.) leaf powder into gluten-free bread formulations: Evaluation of their nutritional, antidiabetic, color, bioactive, textural, and sensory properties.
J Sci Food Agric
September 2025
Department of Nutrition and Dietetics, Hamidiye Faculty of Health Sciences, University of Health Sciences, Istanbul, Türkiye.
Background: This study aimed to develop gluten-free bread from chickpea flour by incorporation of varying levels (0 (B-C), 2.5 (B-1), 5 (B-2), and 10 g kg (B-3)) of madımak leaf powder (MLP), and to investigate its effect on physicochemical and bioactive properties, glycemic index, texture, and sensory attributes.
Results: Moisture ranged from 229 (B-3) to 244 g kg (control), while ash content increased with MLP, reaching 47 g kg in B-3 compared to 15.
An aptasensor-based fluorescent signal amplification strategy for highly sensitive detection of mycotoxins.
Anal Methods
September 2025
Key Laboratory of Biorheological Science and Technology of Ministry of Education, College of Bioengineering, Chongqing University, Chongqing 400044, P. R. China.
Aflatoxin B1 (AFB1) is one of the most toxic mycotoxins that pose great health threats to humans. Herein, an aptasensor-based fluorescent signal amplification strategy is developed for the detection of AFB1. Initially, the AFB1 aptamers labelled with carboxyfluorescein (FAM) are adsorbed onto graphene oxide (GO), triggering energy transfer.
View Article and Find Full Text PDFDecoding Enzymatic Dechlorination with Multiscale Modeling: Mechanistic Insights into Native Haloalkane Dehalogenase from and Its Designed Variants.
ACS Catal
August 2025
Department of Chemistry, University of Southern California, Los Angeles, California 90089, United States.
Chlorinated hydrocarbons are widely used as solvents and synthetic intermediates, but their chemical persistence can cause hazardous environmental accumulation. Haloalkane dehalogenase from (DhlA) is a bacterial enzyme that naturally converts toxic chloroalkanes into less harmful alcohols. Using a multiscale approach based on the empirical valence bond method, we investigate the catalytic mechanism of 1,2-dichloroethane dehalogenation within DhlA and its mutants.
View Article and Find Full Text PDFTransient electronics for sustainability: Emerging technologies and future directions.
Beilstein J Nanotechnol
September 2025
Department of Materials Science and Engineering, Seoul National University, Seoul, 08826 Republic of Korea.
Transient electronics are emerging as a promising class of devices designed to disappear after a defined operational period, addressing growing concerns over sustainability and long-term biocompatibility. Built from biodegradable materials that undergo hydrolysis or enzymatic degradation, these systems are particularly well suited for temporary implantable applications, such as neural monitors, wireless stimulators, and drug delivery vehicles, as well as environmentally benign electronics for soil or aquatic disposal. Despite their potential, key challenges remain in expanding the material set for diverse functionalities, achieving high-density integration for advanced operations, and enabling precise lifetime control through strategies such as protective encapsulation.
View Article and Find Full Text PDFBackgroundRAY1216 is an alpha-ketoamide-based peptide inhibitor of severe acute respiratory syndrome coronavirus type 2 (SARS-CoV-2) major protease (M). This study evaluated the absorption, distribution, metabolism and excretion of [C]-labelled RAY1216 by oral administration.Research design and methodsThis phase Ι study was designed to assess the pharmacokinetics, mass balance and metabolic pathways in 6 healthy Chinese adult men after a single fasting oral administration of 240 mL (containing 400 mg/100 μCi) [C] RAY1216.
View Article and Find Full Text PDF