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Catalytic oxidation, an end-of-pipe treatment technology for effectively purifying volatile organic compounds (VOCs), has received widespread attention. The crux of catalytic oxidation lies in the development of efficient catalysts, with their optimization necessitating a comprehensive analysis of the catalytic reaction mechanism. Two-dimensional (2D) ultra-thin nanomaterials offer significant advantages in exploring the catalytic oxidation mechanism of VOCs due to their unique structure and properties. This review classifies strategies for regulating catalytic properties and typical applications of 2D materials in VOCs catalytic oxidation, in addition to their characteristics and typical characterization techniques. Furthermore, the possible reaction mechanism of 2D Co-based and Mn-based oxides in the catalytic oxidation of VOCs is analyzed, with a special focus on the synergistic effect between oxygen and metal vacancies. The objective of this review is to provide valuable references for scholars in the field.
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http://dx.doi.org/10.1016/j.scitotenv.2024.170748 | DOI Listing |
Angew Chem Int Ed Engl
September 2025
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, LIFM, IGCME, GBRCE for Functional Molecular Engineering, Sun Yat-Sen University, Guangzhou, 510006, China.
Oximes serve as indispensable intermediates in synthetic chemistry, owing to their distinctive C═N─OH structure, conferring highly versatile reactivity. Synthesis of oxime via the electrochemical method has potential advantages, accompanied by the upgrading of industrialization. Herein, we propose a novel strategy by introducing nickel (Ni) mediation to obtain high-spin iron (Fe)(III) in phthalocyanine structure for synthesizing glyoxylate oxime via electrocatalytic nitric oxide (NO) coupling with keto acid.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China.
Enhancing the energy conversion efficiency of fuel cells necessitates optimization of oxygen reduction reaction (ORR) under high-voltage conditions through improved Pt catalysis. This study introduces an electrocatalyst that uniformly anchors a high loading (40 wt%) of small Pt nanoparticles (3.2 nm) on a novel support: tellurium and nitrogen co-mediated graphitized mesoporous carbon (Te-N-GMC).
View Article and Find Full Text PDFEnviron Geochem Health
September 2025
Department of Chemistry, Government Arts College(A), Salem, Tamil Nadu, 636007, India.
A CoO/AgMoO/CeOternary nanocomposites photocatalyst was successfully synthesized through a straightforward ethanol-assisted chemical method. Comprehensive characterization of its structural and optical properties was conducted using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-Vis diffuse reflectance spectroscopy (UV-DRS), and photoluminescence (PL) analysis. XRD analysis confirmed the presence of CoO, AgMoO and CeO in the ternary composite sample.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
Research Center of Advanced Catalytic Materials & Functional Molecular Synthesis, Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process, School of Chemistry & Chemical Engineering, Shaoxing University, Shaoxing, 312000, China; Institute of Chemistry, Chinese Academy of Scien
Inspired by "the composition of catechol and amine groups in the adhesive proteins" of marine mussel and "brick-and-mortar" structure of nacre, we use polydopamine (PDA) as "mortar", graphene oxides (GO) nanosheets as "brick", and Pd ions as interfacial reinforcer, to fabricate nacre-like Pd enhanced PDA functionalized GO membranes (Pd@PDA/GO) with vacuum filtration-assisted assembly method. Meanwhile, in situ reduced Pd nanoclusters by PDA chains were well constrained within the resultant Pd@PDA/GO artificial nacre composites. Good interfacial adhesion with dense packing of the GO nanosheets was further confirmed with sub-nano level microstructure characterization by positron annihilation lifetime spectroscopy.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
Department of Chemical and Materials Engineering, National Yunlin University of Science and Technology, 123 University Road, Section 3, Douliou, Yunlin 64002, Taiwan.
Urea electrolysis holds tremendous promise to remediate urea-containing wastewater and produce cost-effective hydrogen. Achieving highly efficient and durable electrocatalysts to drive the anodic urea oxidation reaction (UOR) is paramount to promote its practical applications. Herein, electroless deposition, a scalable, cost-effective, and energy-saving approach, is used to obtain amorphous Ni-Co-P nanoparticles.
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