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Ergodicity, a fundamental concept in statistical mechanics, is not yet a fully understood phenomena for closed quantum systems, particularly its connection with the underlying chaos. In this review, we consider a few examples of collective quantum systems to unveil the intricate relationship of ergodicity as well as its deviation due to quantum scarring phenomena with their classical counterpart. A comprehensive overview of classical and quantum chaos is provided, along with the tools essential for their detection. Furthermore, we survey recent theoretical and experimental advancements in the domain of ergodicity and its violations. This review aims to illuminate the classical perspective of quantum scarring phenomena in interacting quantum systems.
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http://dx.doi.org/10.1088/1361-648X/ad1bf5 | DOI Listing |
ACS Nano
September 2025
Department of Chemical Physics, Key Laboratory of Precision and Intelligent Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China.
The coupling between transition metal dichalcogenides (TMDCs) and SrTiO has recently emerged as a fertile platform for discovering interfacial phenomena, where particle interactions, lattice coupling, and dielectric screening give rise to interesting physical effects. These hybrid systems hold significant promise for two-dimensional (2D) electronics, ferroelectric state control, and metastable phase engineering. However, effective modulation of the interfacial electronic structure remains a critical challenge.
View Article and Find Full Text PDFJ Comput Chem
September 2025
Wilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie, Leipzig University, Leipzig, Germany.
We investigated primary and secondary geometric isotope effects (H, D, T) on charge-inverted hydrogen bonds (CIHB) and dihydrogen bonds (DHB) using nuclear-electronic orbital density functional theory (NEO-DFT). The dianionic but electrophilic boron cluster [BH] served as a bonding partner, exhibiting a negatively polarized hydrogen atom in the BH bond. CIHB systems included interactions with Lewis acids (AlH, BH, GaH) and carbenes (CF, CCl, CBr), while DHBs were analyzed with NH, HF, HCl, and HBr.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2025
Department of Chemistry, Graduate School of Science and Technology, Kwansei Gakuin University, 1 Gakuen Uegahara, Sanda, Hyogo 669-1330, Japan.
Hybrid systems (HSs) of quantum dots (QDs) and molecular photoswitches exhibit luminescence switching of QDs based on energy transfer and have garnered attention for their potential applications in sensors and optical memories. In HSs, the chemical composition, such as the number of attached ligands, is inherently distributed, posing challenges for extracting the energy transfer process from the QDs to a single acceptor molecule. The stochastic model, assuming a Poisson distribution for the number of acceptors, proves to be an effective approach for extracting the process.
View Article and Find Full Text PDFMikrochim Acta
September 2025
Faculty of Life Science and Technology, Kunming University of Science and Technology, Yunnan Province, 650500, China.
Iron-cerium co-doped carbon dots (Fe,Ce-CDs) were synthesized by one-step hydrothermal method using tartaric acid and L-tryptophan as ligands. Fe,Ce-CDs shows excellent peroxidase-like (POD) activity and nitrite (NO) can promote the oxidation of 3,3',5,5'-tetramethylbenzidine (TMB) to its blue oxidation product (oxTMB) due to the formation of ∙NO free radical. NO further react with oxTMB to form a yellow color via diazotization resulting in the absorbance Change at 450 nm.
View Article and Find Full Text PDFNature
September 2025
Department of Physics, Harvard University, Cambridge, MA, USA.
Quantum simulations of many-body systems are among the most promising applications of quantum computers. In particular, models based on strongly correlated fermions are central to our understanding of quantum chemistry and materials problems, and can lead to exotic, topological phases of matter. However, owing to the non-local nature of fermions, such models are challenging to simulate with qubit devices.
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