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To address the electromagnetic wave (EMW) pollution issues caused by the development of electronics and wireless communication technology, it is urgent to develop efficient EMW-absorbing materials. With controllable composition, diverse structure, high porosity, and large specific surface area, metal-organic framework (MOF) derivatives have sparked the infinite passion and creativity of researchers in the electromagnetic field. Against the challenges of poor inherent impedance matching and insufficient attenuation capability of pure MOF derivative, designing and developing MOF derivative-based composites by compounding MOF with other materials, such as graphene, CNTs, MXene, and so on, has been an effective strategy for constructing high-efficiency EMW absorbing materials. This review systematically expounds the research progress of MOF derivative-based composite strategies, and discusses the challenges and opportunities faced by MOF derivatives in the field of EMW absorption. This work can provide some good ideas for researchers to design and prepare high-efficiency MOF-based EMW absorbing materials in applications of next-generation electronics and aerospace.
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http://dx.doi.org/10.1016/j.isci.2023.107132 | DOI Listing |
J Am Chem Soc
September 2025
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China.
Metal-organic frameworks (MOFs) are distinguished by their structural diversity, tunable electronic properties, and exceptional performance in various applications. Notably, the electron-donating ability of ligands significantly enhances the ligand-to-metal charge transfer (LMCT) processes within these frameworks, thereby promoting efficient charge migration. Herein, we developed two electron-rich macrocyclic ligands derived from phenothiazine- and phenoxazine-functionalized calix[3]arenes, alongside their corresponding cobalt-coordinated MOFs.
View Article and Find Full Text PDFFront Chem
August 2025
Faculty of Educational Sciences, Al-Ahliyya Amman University, Amman, Jordan.
In this study, a novel hybrid hydrogel incorporating a scandium-based metal-organic framework (scandium-integrated MOF-hydrogel hybrid) was developed using scandium nitrate, 1,4-naphthalenedicarboxylic acid, oxidized pectin, and chitosan. The synthesized scandium-integrated MOF-hydrogel hybrid demonstrated remarkable dual-functionality in both the adsorption of hazardous dye pollutants and the inhibition of pathogenic bacteria commonly found in wastewater. Characterization of the scandium-integrated MOF-hydrogel hybrid was performed using FT-IR, XRD, SEM, EDAX, CHNO elemental, BET, and XPS analyses, confirming successful MOF integration and a porous, reactive surface.
View Article and Find Full Text PDFChem Commun (Camb)
September 2025
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, PR China.
The MOF-derived Pd-CeO/NC catalyst exhibited enhanced formic acid electrooxidation activity due to interfacial electronic reconstruction, which downshifted the Pd d-band centre, thereby promoting the indirect oxidation of HCOOH and facilitating CO* oxidation.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Key Laboratory of Atomic and Molecular Physics & Functional Materials of Gansu Province, College of Physics and Electronic Engineering, Northwest Normal University, Lanzhou 730070, China.
Overcoming the persistent challenges of high operating temperatures and poor selectivity in metal oxide semiconductor (MOS) gas sensors, this work enhances defect sites in the sensing material through heterostructure construction and builds mesoporous architectures using MOF-derived carbon skeletons as templates. The synergistic effects of multiple mechanisms significantly improve gas-sensing performance, successfully fabricating a ZnO/PCS flexible room-temperature gas sensor with exceptional room-temperature DMF detection capabilities. The nitrogen-containing porous carbon skeletons (PCSs) template shows a stable mesoporous microstructure with large pore volume.
View Article and Find Full Text PDFAnal Chim Acta
November 2025
The Key Lab of Health Chemistry & Molecular Diagnosis of Suzhou, College of Chemistry, Chemical Engineering & Materials Science, Soochow University, Suzhou, 215123, PR China; Center of Self-Propelled Nanotechnologies, Suzhou Industrial Park Institute of Services Outsourcing, Suzhou, 215123, PR China
Background: Of the mycotoxins, aflatoxin is the most significant. The detection of aflatoxin B1 (AFB1) is crucial for ensuring food safety, as this highly carcinogenic toxin readily contaminates crops such as grains and nuts, and timely detection can effectively prevent associated health risks. The selection of luminophores is of paramount importance in the detection of ECL (electrochemiluminescence).
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