Visible-light-driven photocatalytic degradation of tetracycline hydrochloride by Z-scheme AgPO/1T@2H-MoS heterojunction: Degradation mechanism, toxicity assessment, and potential applications.

Residual antibiotics in wastewater threaten living organisms and the ecosystem, while the photocatalytic process is recognized as one of the most eco-friendly and promising technologies for the treatment of antibiotic wastewater. In this study, a novel Z-scheme AgPO/1T@2H-MoS heterojunction was synthesized, characterized, and used for the visible-light-driven photocatalytic degradation of tetracycline hydrochloride (TCH). It was found that AgPO/1T@2H-MoS dosage and coexisting anions had significant effects on the degradation efficiency, which could reach up to 98.9 % within 10 min under the optimal condition. Combing experiments and theoretical calculations, the degradation pathway and mechanism were thoroughly investigated. The excellent photocatalytic property of AgPO/1T@2H-MoS was achieved attributed to the Z-scheme heterojunction structure, which remarkably inhibited the recombination of photoinduced electrons and holes. The potential toxicity and mutagenicity for TCH and generated intermediates were evaluated, which revealed the ecological toxicity of antibiotic wastewater was reduced effectively during the photocatalytic degradation process.