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By inserting a tricoordinate B atom into an indolo[3,2,1-]carbazole precursor, an efficient fused multiple resonance-induced thermally activated delayed fluorescence emitter was prepared, which exhibits a narrowband emission and a considerable reverse intersystem crossing rate. The corresponding organic light-emitting diode displays an external quantum efficiency of 27.2% with a suppressed efficiency roll-off.
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http://dx.doi.org/10.1039/d2cc06280a | DOI Listing |
Biosens Bioelectron
August 2025
State Key Laboratory of Frigid Zone Cardiovascular Diseases (SKLFZCD), Research Center for Innovative Technology of Pharmaceutical Analysis, College of Pharmacy, Harbin Medical University, Heilongjiang, 150081, PR China; Research Unit of Health Sciences and Technology (HST), Faculty of Medicine Univ
Rapid detection of toxic molecules in biological fluids is crucial for clinical diagnosis, emergency toxicology, and forensic investigations. However, traditional methods such as liquid chromatography and gas chromatography are limited of complex sample preparation, time - consuming detection, and lack a basis for detecting different matrices and multiple toxicants. Herein, a two-step enhancement platform Ag@BOCPs based on surface-enhanced Raman spectroscopy (SERS) was developed, overcoming the limitations of the poor universality of the conventional silver nanoparticle.
View Article and Find Full Text PDFChem Sci
April 2025
Shenzhen Key Laboratory of New Information Display and Storage Materials, College of Materials Science and Engineering, Shenzhen University Shenzhen 518060 P. R. China
Multiple resonance-induced thermally activated delayed fluorescence (MR-TADF) materials with pure-red gamut are in demand for high-definition organic light-emitting diode (OLED) displays. To achieve efficient pure-red OLEDs with excellent color purity, we report three novel MR-TADF emitters: PhCzBN, PhBCzBN, and BCzBN, which integrate a dibenzo[,]carbazole segment into a para-boron/oxygen-embedded framework, resulting in the progressive extension of the molecular conjugation. This extension of the π-conjugated skeleton enhances frontier molecular orbital (FMO) delocalization and red-shifts the emission, yielding pure-red emission in toluene with satisfactory peak positions and narrow linewidths.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
May 2025
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, 130012, P.R. China.
The demand for ultra-high-definition display technology has spurred the prosperity of multiple resonance induced thermally activated delayed fluorescence (MR-TADF) materials with narrow full-width at half-maximum (FWHM) and high efficiency, making them highly promising candidates for high-color-purity organic light-emitting diodes (OLEDs) displays. Indolocarbazole, a highly rigid aza-polycyclic aromatic hydrocarbon framework, has shown significant potential as a building block for constructing MR-TADF emitters with ultra-narrowband emission (<20 nm). However, it remains a great challenge to construct ultra-narrowband indolocarbazole-embedded MR-TADF emitters with emission maxima less than 500 nm.
View Article and Find Full Text PDFSubwavelength light trapping in periodic structures with high quality (Q) factors is discovered to hold strong light-matter interactions for a variety of applications. Although dual-band or even multiple-band high-Q resonances are applicable to extend the operation range of a nanophotonic device, manipulating the high-Q modes individually is a necessity to implement plural intriguing applications in one system as well as optimize the capabilities across each spectrum. In this work, a novel approach is presented to independently control dual high-Q modes with distinct origins in an all-dielectric metasurface system.
View Article and Find Full Text PDFAdv Mater
September 2024
Madrid Institute for Advanced Studies, IMDEA Nanoscience, C/ Faraday 9, Ciudad Universitaria de Cantoblanco, Madrid, 28049, Spain.
Current research on organic light emitters which utilize multiple resonance-induced thermally activated delayed fluorescence (MR-TADF) materials is gaining significant interest because of the materials' ability to efficiently generate color-pure blue emission. However, the underlying reasons for high color purity remain unclear. It is shown here that these emitters share a common electronic basis, which is deduced from resonance structure considerations following Clar's rule, and which is termed as "poly-heteroaromatic omni-delocalization" (PHOD).
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