Innovations in the Development of Promising Adsorbents for the Remediation of Microplastics and Nanoplastics - A Critical Review.

Microplastics and nanoplastics are being assumed as emerging toxic pollutants owing to their unique persistent physicochemical attributes, chemical stability, and nonbiodegradable nature. Owing to their possible toxicological impacts (not only on aquatic biota but also on humans), scientific communities are developing innovative technologies to remove microplastics and nanoplastics from polluted waters. Various technologies, including adsorption, coagulation, photocatalysis, bioremediation, and filtration, have been developed and employed to eliminate microplastics and nanoplastics. Recently, adsorption technology has been getting great interest in capturing microplastics and nanoplastics and achieving excellent removal performance. Therefore, this review is designed to discuss recent innovations in developing promising adsorbents for the remediation of microplastics and nanoplastics from wastewater and natural water. The developed adsorbents have been classified into four main classes: sponge/aerogel-based, metal-based, biochar-based, and other developed adsorbents, and their performance efficiencies have been critically examined. Further, the influence of various pertinent factors, including adsorbents' characteristics, microplastics/nanoplastics' characteristics, solution pH, reaction temperature, natural organic matter, and co-existing/interfering ions on the removal performance of advanced adsorbents, have been critically assessed. Importantly, the particle application of the developed adsorbents in removing microplastics and nanoplastics from natural water has been elucidated. In addition, barriers to market penetration of the developed adsorbents are briefly discussed to help experts transfer adsorption-based technology from laboratory-scale to commercial applications. Finally, the current knowledge gaps and future recommendations are highlighted to assist scientific communal for improving adsorption-based technologies to battle against microplastics and nanoplastics pollution.