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The novel coronavirus (COVID-19), first identified at the end of December 2019, has significant impacts on all aspects of human society. In this study, we aimed to assess the ambient air quality patterns associated to the COVID-19 outbreak in the Yangtze River Delta (YRD) region using a random forest (RF) model. To estimate the accuracy of the model, the cross-validation (CV), determination coefficient R, root mean squared error (RMSE) and mean absolute error (MAE) were used. The results demonstrate that the RF model achieved the best performance in the prediction of PM (R = 0.78, RMSE = 8.81 μg/m), PM (R = 0.76, RMSE = 6.16 μg/m), SO (R = 0.76, RMSE = 0.70 μg/m), NO (R = 0.75, RMSE = 4.25 μg/m), CO (R = 0.81, RMSE = 0.4 μg/m) and O (R = 0.79, RMSE = 6.24 μg/m) concentrations in the YRD region. Compared with the prior two years (2018-19), significant reductions were recorded in air pollutants, such as SO (-36.37%), followed by PM (-33.95%), PM (-32.86%), NO (-32.65%) and CO (-20.48%), while an increase in O was observed (6.70%) during the COVID-19 period (first phase). Moreover, the YRD experienced rising trends in the concentrations of PM, PM, NO and CO, while SO and O levels decreased in 2021-22 (second phase). These findings provide credible outcomes and encourage the efforts to mitigate air pollution problems in the future.
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http://dx.doi.org/10.1016/j.chemosphere.2022.137638 | DOI Listing |
Org Biomol Chem
September 2025
Department of Chemistry, Indian Institute of Engineering Science and Technology (IIEST), Shibpur, P O- Botanic Garden, Howrah- 711103 (WB), India.
A simple yet efficient method involving a visible-light-induced direct, regioselective chalcogenation of indoloquinoxaline derivatives has been developed. Thiols, disulfides and diselenides were found to be efficient as chalcogenating agents in the presence of Rose Bengal as a photosensitizer. This photoinduced C-H functionalization a cross-dehydrogenative-coupling (CDC) protocol was carried out at ambient temperature under an open-air atmosphere.
View Article and Find Full Text PDFEcotoxicol Environ Saf
September 2025
China CDC Key Laboratory of Environment and Population Health, National Institute of Environmental Health, Chinese Center for Disease Control and Prevention, Beijing 100021, China; National Key Laboratory of Intelligent Tracking and Forecasting for Infectious Diseases, National Institute of Environm
New evidence has revealed ambient fine particulate matter < 2.5 μm (PM) may have endocrine disrupting effect, such as thyroid hormone disorder, while which PM constituents contributed to the effect was debatable. The study aimed to identify the specific PM constituents regarding to acute endocrine disrupting effect.
View Article and Find Full Text PDFJ Hazard Mater
September 2025
Institute of Environment, Florida International University, 3000 NE 151st St., Biscayne Bay Campus, North Miami, FL 33181, USA; Department of Chemistry and Biochemistry. Florida International University, 11200 SW 8th Street, Modesto A. Maidique Campus, Miami, FL 33199, USA. Electronic address: nsoar
Per- and polyfluoroalkyl substances (PFAS) are man-made pollutants widely used in industrial and consumer products, known to pose significant health risks. While their occurrence in water, soil, and food has been extensively studied, limited research has focused on ambient air, particularly in the U.S.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
The Steve Sanghi College of Engineering, Mechanical Engineering, Northern Arizona University, Flagstaff, Arizona 86011, United States.
This study investigates the HO and CO sorption behavior of two chemically distinct polystyrene-divinylbenzene-based ion exchange sorbents: a primary amine and a permanently charged strong base quaternary ammonium (QA) group with (bi)carbonate counter anions. We compare their distinct interactions with HO and CO through simultaneous thermal gravimetric, calorimetric, gas analysis, and molecular modeling approaches to evaluate their performance for dilute CO separations like direct air capture. Thermal and hybrid (heat + low-temperature hydration) desorption experiments demonstrate that the QA-based sorbent binds both water and CO more strongly than the amine counterparts but undergoes degradation at moderate temperatures, limiting its compatibility with thermal swing regeneration.
View Article and Find Full Text PDFInorg Chem
September 2025
Yunnan Key Laboratory of Crystalline Porous Organic Functional Materials, College of Chemical and Materials Engineering, Qujing Normal University, Qujing 655011, China.
Sequential assembly of donor-acceptor components at the molecular level within a MOF is an effective strategy to achieve efficient electron-hole separation for enhancing the activity of photocatalysts. Meanwhile, the highly efficient and selective functionalization of tetrahydroisoquinoline (THIQ) under mild conditions remains an urgent demand in both the scientific and industrial communities. This work reports a donor-acceptor MOF photocatalyst () constructed by the coordinated assembly of donor and acceptor components, in which a naphthalene unit serves as an electron donor and a perylenediimide unit as an electron acceptor.
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