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In the current work, several composites made with fly ash reinforcements are used to conduct electrical discharge machining (EDM) on stainless steel that is commercially accessible. Four composites were prepared with 2.5 to 10% reinforcement of fly ash with steps of 2.5%, copper is used as the matrix material. The specimens were created using the powder metallurgy method, which involved compaction pressures of 450 MPa and 900 °C for 90 min of sintering. The prepared composites are used as the electrode tool for EDM. EDM studies were carried out at two different current amplitudes (5A and 15A) by maintaining the Pulse on time (100 µs), Pulse off time (50 µs), and the depth of machining as 2 mm. The findings show that the addition of more fly ash to the copper matrix increased the material removal rate when cutting the SS304 plate and had a negative impact on the tool. The composite loses its ability to transfer heat during machining as the level of fly ash increases, raising the temperature in the copper matrix and causing the copper to melt more quickly at the electrode interface during machining, leading to increased electrode wear. While tool life was reduced because of the increase in current amplitude, machinability was enhanced.
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http://dx.doi.org/10.3390/ma15196735 | DOI Listing |
Bioresour Technol
September 2025
State Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan 430074, China.
The pyrolysis of flue-cured tobacco stalks (TS) faces challenges such as low bio-oil value and utilization efficiency. Existing studies have overlooked the anatomical heterogeneity of tobacco stalks, thereby limiting the directional regulation of high-value components, such as nicotine and phenolic compounds. This study divides TS into the husk (TSH), xylem (TSX), and pith (TSP), and investigates their physicochemical properties, pyrolysis behavior (through TGA and fixed-bed pyrolysis experiments), and interactions.
View Article and Find Full Text PDFEnviron Res
September 2025
National Key Laboratory of Deep Coal Mining Safety and Environmental Protection, Anhui University of Science and Technology, Huainan, 232001, Anhui, China.
Zeolite synthesis from fly ash offers recycling and environmental benefits for carbon dioxide capture, but varying fly ash composition from different sources has different compositions, leading to inconsistent adsorption results. To achieve high CO adsorption performance and stability in zeolite synthesis from fly ash systems, this study established an element-controlled simulated fly ash system with Ca/Fe gradient differences. Hydrothermal synthesis yielded zeolites with optimized oxide ratios for CO adsorption.
View Article and Find Full Text PDFArch Environ Contam Toxicol
September 2025
Ecole Polytechnique Fédérale de Lausanne (EPFL), School of Architecture, Civil and Environmental Engineering, 1015, Lausanne, Switzerland.
Pollution from past industrial activities can remain unnoticed for years or even decades because the pollutant has only recently gained attention or been identified by measurements. Modeling the emission history of pollution is essential for estimating population exposure and apportioning potential liability among stakeholders. This paper proposes a novel approach for reconstructing the history of polychlorinated dibenzo-p-dioxin (PCDD) and polychlorinated dibenzofuran (PCDF) pollution from municipal solid waste incinerators (MSWIs) with unknown past emissions.
View Article and Find Full Text PDFEnviron Res
September 2025
Materials Science, Engineering, and Commercialization (MSEC) Program, Texas State University, San Marcos, TX-78666, USA; Department of Engineering Technology, Texas State University, San Marcos, TX-78666, USA.
Fly ash (FA) landfills are overflowing with materials, and unexplored waste streams like waste spent garnet (WSG) and waste foundry sand (WFS) are often dumped in onsite storage spaces, limiting land availability for future use and exacerbating environmental concerns related to waste disposal. Therefore, this research proposes recycling FA to produce reclaimed FA (RFA) as a binder, replacing 40-60% of ground granulated blast furnace slag (GGBFS) and 30-50% of river sand (RS) with WSG and WFS to produce geopolymers. The performance of geopolymers was assessed under different curing regimes, including ambient-temperature curing (ATC), ambient-temperature water curing (AWC), high-temperature curing (HTC), and high-temperature water curing (HWC).
View Article and Find Full Text PDFJ Environ Manage
September 2025
Interdisciplinary Research Center for Construction and Building Materials, Department of Materials Science and Engineering, King Fahd University of Petroleum & Minerals, Dhahran, Saudi Arabia.
The disposal of municipal solid waste incineration fly ashes (MSWI-FA) is complicated by soluble chlorides, which increase the risk of heavy metals (HMs) leaching toxicity and hinder the further use of remediated MSWI-FA. In this study, the self-assembly potentiality of magnesium oxychloride cement (MOC) in geopolymerization was explored and utilized to enhance the solidification/stabilization (S/S) of the MSWI-FA. The MOC-self-assembled geopolymerization kinetics can be suitably described by the JMAK model.
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