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Among global efforts facing plastic pollution, their gradual replacement with alternative materials has gained strength during the last decade. We identified five stakeholders and their respective key participation in the chain of bio-based, biodegradable and compostable plastics (BBCP), which have contributed to several flaws on governance of these materials. The widespread unfamiliarity of the consumers about biodegradability concepts has been leading to misguided purchase decisions and disposal practices, along with possible littering behavior. Simultaneously, the adoption of greenwashing practices by stores and manufacturers contribute to disseminating misguided decisions on plastic consumption. Such issues are further aggravated by the lack of certification standards concerning the impact of littering, including the assessment of persistency and toxicity, also covering those made with biodegradable plastics.". Moreover, even though such alternative polymers were originally conceived as a strategy to minimize plastics pollution, the almost inexistence of specific regulatory frameworks in different political scales may convert them in a relevant part of the problem. Therefore, the governance systems and management strategies need to incorporate BBCP as potentially hazardous waste as they do for conventional plastics.
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http://dx.doi.org/10.1016/j.jenvman.2022.116074 | DOI Listing |
RSC Adv
September 2025
Department of Chemical Engineering and Green Technology, Institute of Chemical Technology (ICT) Mumbai Maharashtra 400019 India
The sustainable synthesis of bio-based monomers from renewable biomass intermediates is a central goal in green chemistry and biorefinery innovation. This study introduces a synergistic catalytic-enzymatic strategy for the efficient and eco-friendly oxidation of 5-hydroxymethylfurfural (5-HMF) into 2,5-furandicarboxylic acid (FDCA), a key monomer for next-generation biodegradable plastics. The catalytic phase employed non-noble metal catalysts, MnO and Co-Mn supported on activated carbon (Co-Mn/AC), under mild batch reaction conditions at 90 °C.
View Article and Find Full Text PDFFront Microbiol
August 2025
Key Laboratory for Waste Plastics Biocatalytic Degradation and Recycling, College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing, China.
Polyurethane (PU), a segmented block copolymer with chemically resistant urethane linkages and tunable architecture, presents persistent biological recycling challenges. This study presents a Bacterial Laccase-Mediated System (BLMS) derived from for efficient degradation of polyester- and polyether-PU. Utilizing the laccase CotA and mediator 2,2'-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) (ABTS), the BLMS demonstrated effective de polymerization of both commercial and self-synthesized PU foams, including polyester- and polyether-types.
View Article and Find Full Text PDFFEBS Open Bio
September 2025
Department of Biotechnology and Life Sciences, University of Insubria, Varese, Italy.
The global accumulation of plastic waste, exceeding 360 million tonnes annually, represents a critical environmental challenge due to their widespread use and extreme recalcitrance in natural environments. Furthermore, the end-of-life processing of bioplastics, which are often marketed as eco-friendly, remains problematic, with biodegradation often requiring industrial conditions. Enzyme-based depolymerization of polyesters, such as polyethylene terephthalate (PET) and bioplastics (e.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
School of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou, 450000, China.
With growing public attention to environmental issues and sustainable development, biodegradable bio-based plastics have attracted widespread interest. This study reveals the chemical-physical synergistic regulation mechanism of biodegradable PLA/PBAT blends through the synergistic modification of epoxidized natural rubber (ENR) and epoxy chain extender (ADR). Interfacial interaction analysis shows that PBAT tends to encapsulate ENR to form aggregates.
View Article and Find Full Text PDFBiotechnol Rep (Amst)
September 2025
Technical University of Munich, Germany, TUM Campus Straubing for Biotechnology and Sustainability, Bioprocess Engineering, Uferstraße 53, D-94315 Straubing, Germany.
Exopolysaccharides are biopolymers with wide-ranging industrial applications. To substitute fossil-based by bio-based, biodegradable polymers, exopolysaccharide production needs to become much more efficient. Pullulan, produced by , is popular for its unique properties like film-formation, adhesiveness, biodegradability, etc.
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