Polymer-Induced Emission-Active Fluorine-Embedded Carbon Dots for the Preparation of Warm WLEDs with a High Color Rendering Index.

Exploration of many strategies has continuously contributed to producing aggregation-induced red-emissive carbon dots (CDs). In this work, we designed fluorine-embedded (F-embedded) CDs from 1,2,4-triaminobenzene, thiourea, and ammonium fluoride (NHF) exhibiting polymer-induced emission (PIE). The PIE phenomenon of fluorescent CDs is obtained in poly(vinyl alcohol) (PVA), showing emissions at 611 and 617 nm in the dispersed and solid states, respectively. The CDs exhibited a red shift of 28 nm in the PVA solution because PVA hydroxyl groups formed a robust bridge-like H-bonding network between CDs. The fluorine embedded in CDs enhanced the H-bond affinity toward PVA. It showed that this H-bond restricted the coupling of CDs' surface states and inhibited the nonirradiation transfer. For the solid state, surface PVA chains eliminated the π-π interaction of the conjugated core and constructed a self-quenching resistance polymeric system around CDs. As a result, CDs showed an unexpected red shift of fluorescence emission in PVA. Furthermore, white light-emitting diodes (WLEDs) have a correlated color temperature (CCT) of 5232 K, and a high color rendering index of 95 has been fabricated by integrating the red- and green-emissive films over the UV LEDs. Interestingly, the as-synthesized CDs showed room temperature phosphorescence (RTP), which enabled us to employ the CDs in double-security protection. Simultaneously, CDs have been used in fingerprint detection.