Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
Tungsten-containing formate dehydrogenase from AM1 (FoDH1)-a promising biocatalyst for the interconversion of carbon dioxide/formate and nicotine adenine dinucleotide (NAD)/NADH redox couples-was investigated using structural biology and bioelectrochemistry. FoDH1 is reported to be an enzyme that can realize "direct electron transfer (DET)-type bioelectrocatalysis." However, its 3-D structure, electrode-active sites, and electron transfer (ET) pathways remain unclear. The ET pathways were investigated using structural information, electrostatic interactions between the electrode and the enzyme, and the differences in the substrates. Two electrode-active sites and multiple ET pathways in FoDH1 were discovered.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d2cc01541b | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Electron-Rich Macrocycle-Based Metal-Organic Frameworks for Efficient Photocatalytic CO Reduction.
J Am Chem Soc
September 2025
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China.
Metal-organic frameworks (MOFs) are distinguished by their structural diversity, tunable electronic properties, and exceptional performance in various applications. Notably, the electron-donating ability of ligands significantly enhances the ligand-to-metal charge transfer (LMCT) processes within these frameworks, thereby promoting efficient charge migration. Herein, we developed two electron-rich macrocyclic ligands derived from phenothiazine- and phenoxazine-functionalized calix[3]arenes, alongside their corresponding cobalt-coordinated MOFs.
View Article and Find Full Text PDFEngineering Brønsted Acidic Microenvironments via Strong Metal-Support Interaction in Single-Atom Pd/CeO for Acid-Free Acetalization Catalysis.
Inorg Chem
September 2025
College of Chemistry and Materials Science, The key Laboratory of Functional Molecular Solids, Ministry of Education, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Provincial Engineering Laboratory for New-Energy Vehicle Battery Energy-Storage Materia
Conventional acid-catalyzed acetalization faces significant challenges in catalyst recovery and poses environmental concerns. Herein, we develop a CeO-supported Pd single-atom catalyst (Pd/CeO) that eliminates the reliance on liquid acids by creating a localized H-rich microenvironment through heterolytic H activation. X-ray absorption near-edge structure and extended X-ray absorption fine structure analyses confirm the atomic dispersion of Pd via Pd-O-Ce coordination, while density functional theory (DFT) calculations reveal strong metal-support interactions (SMSI) that facilitate electron transfer from CeO oxygen to Pd, downshifting the Pd d-band center and optimizing H activation.
View Article and Find Full Text PDFExploitation of Biodiversity in Bioeconomy: Examples, Opportunities, and Challenges.
Adv Biochem Eng Biotechnol
September 2025
Institute of Process Engineering in Life Sciences, Electrobiotechnology, Karlsruhe Institute of Technology, Karlsruhe, Germany.
While bioprocesses using Escherichia coli, Corynebacterium glutamicum, various species of Bacillus, lactic acid bacteria, Clostridia, the yeasts Saccharomyces cerevisiae and Pichia pastoris, fungi such as Aspergillus niger, and Chinese hamster ovary cells are well established, the high level of microbial diversity has not yet been exploited industrially. However, the use of alternative organisms has the potential to significantly expand the process window of bioprocesses. These extensions include the use of alternative substrates (e.
View Article and Find Full Text PDFReal-Space Quantitative Molecular Analysis at Single-Molecule Resolution.
J Am Chem Soc
September 2025
Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou 215123, Jiangsu P. R. China.
Advances in molecular analysis and characterization techniques should revolutionize the methods for scientific exploration across physics, chemistry, and biology, fundamentally overturning our understanding of interactions and processes that govern molecular behavior at the microscopic level. Currently, the absence of a molecular analysis method that can both quantify molecules and achieve single-molecule spatial resolution hinders our study of complex molecular systems in sorption and catalysis. Here, we propose a quantitative analysis strategy for small molecules confined in ZSM-5, a zeolite material extensively used in catalysis and gas separation, based on low-dose transmission electron microscopy.
View Article and Find Full Text PDFChaos aided regime of laser/electromagnetic energy absorption by plasma.
Chaos
September 2025
Department of Physics, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India.
The absorption of laser energy by plasma is of paramount importance for various applications. Collisional and resonant processes are often invoked for this purpose. However, in some contexts (e.
View Article and Find Full Text PDF