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Article Abstract
Reaction induced Pd Bi /SiC catalysts exhibit excellent catalytic activity (92% conversion of benzyl alcohol and 98% selectivity of benzyl aldehyde) and stability (time on stream of 200 h) in the gas phase oxidation of alcohols at a low temperature of 240 °C due to the formation of Pd-BiO species. TEM indicates that the agglomeration of the 5.8 nm nanoparticles is inhibited under the reaction conditions. The transformation from inactive PdO-BiO to active Pd-BiO under the reaction conditions is confirmed elaborately by XRD and XPS.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057962 | PMC |
| http://dx.doi.org/10.1039/d0ra07859j | DOI Listing |
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