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Article Abstract
Hybrids of reduced graphene oxide (rGO) and metal/metal oxide (Pt, NiO/Ni(OH), CoO, FeO) nano particle were prepared by reduction of graphene oxide (GO) and metal ion (Pt, Ni, Co, Fe) hybrids. The M-rGO hybrids (M = Pt, Ni-, Co and Fe) were justified for the transformation of glucose to 5-hydroxymethylfurfural (5-HMF). High glucose → 5-HMF conversion was yielded depending on the nature of the M-rGO catalyst. The Ni-rGO showed the highest 5-HMF yield. The conversion reaction tuned to the optimized state under a microwave-assisted reaction accomplished by using Ni-rGO. In such case, the conversion rate was 99% with a 5-HMF yield of 75%. In order to improve both the conversion and yield, NiGO-FD was prepared by a freeze-dry method. The NiGO-FD remarkably showed the highest conversion of 99% and 5-HMF yield of 95%. Beside the biomass transformation process, the physico-chemical strategy employed herein for multiplying the catalytic efficiency might be justified for catalyzing similar reactions.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050549 | PMC |
| http://dx.doi.org/10.1039/d0ra01009j | DOI Listing |
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