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Generally, when an arbitrary polarized light beam is reflected or refracted from an isotropic interface, the spin splitting in photonic spin Hall effect (SHE) shows asymmetry properties. In this paper, we theoretically propose a phase compensation scheme to achieve the transformation from asymmetric spin splitting to symmetric spin splitting in photonic SHE. We experimentally acquire the spin splitting after phase compensation in the case of a 45 degrees linear polarized Gaussian light beam totally internally reflected from a prism-air interface. Particularly, whether or not phase compensation, the transverse shift of total barycenter of reflected field [i.e., the Imbert-Fedorov (IF) shift] does not change. These findings can solve this problem that asymmetric spin splitting cannot be observed by weak measurements.
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http://dx.doi.org/10.1364/OE.456406 | DOI Listing |
J Chem Phys
September 2025
Department of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, Mlynská dolina, Ilkovičova 6, SK-84215 Bratislava, Slovakia.
An explicitly correlated extension of a pair-function based perturbation theory is presented. The reference is obtained as the antisymmetrized product of strongly orthogonal geminals, termed Strictly Localized Geminals (SLG), which can capture static correlation at mean-field cost. Geminals entering SLG are spin unrestricted, in general, and are expanded in the one-electron basis of the natural orbitals of the unrestricted Hartree-Fock wavefunction.
View Article and Find Full Text PDFDalton Trans
September 2025
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of, Sciences, Chernogolovka, Moscow region 142432, Russia.
Neutral iron(III) and iron(II) complexes based on the pyruvic acid thiosemicarbazone (Hthpy) ligand [Fe(Hthpy)(thpy)] (1) and [Fe(Hthpy)] (2) were synthesized, and deeper insights into magneto-structural correlation were gained by FT-IR spectroscopy, single crystal X-ray crystallography, dc magnetic characterization, Fe Mössbauer spectroscopy, and DFT calculations. The X-ray structures of complex 1 were established for the HS ( = 5/2) state at 295 K and the LS ( = 1/2) state at 150 K. The crystal packing of 1 at these temperatures corresponds to the triclinic 1̄ symmetry and contains pairs of [Fe(Hthpy)(thpy)] complexes interconnected by a shortened S⋯S contact.
View Article and Find Full Text PDFJ Phys Condens Matter
September 2025
Department of Physics, Tuskegee University, 1200 West Montgomery Road, 106 Chappie James, Tuskegee, Alabama, 36088-1920, UNITED STATES.
Spin qubit defects in two-dimensional materials have a number of advantages over those in three-dimensional hosts including simpler technologies for the defect creation and control, as well as qubit accessibility. In this work, we select the VBCB defect in the hexagonal boron nitride (hBN) as a possible optically controllable spin qubit and explain its triplet ground state and neutrality. In this defect a boron vacancy is combined with a carbon dopant substituting the closest boron atom to the vacancy.
View Article and Find Full Text PDFAdv Mater
September 2025
School of Materials Science and Engineering, Anhui University, Hefei, 230601, China.
Modulating the electronic structure of catalysts to maximize their power holds the key to address the challenges faced by zinc-iodine batteries (ZIBs), including the shuttle effect and slow redox kinetics at the iodine cathode. Herein, oxygen vacancies is innovatively introduced into CoO lattice to create high-spin-state Co active sites in nonstoichiometric CoO nanocrystals supported by carbon nanofibers (H-CoO/CNFs). This simple strategy intensifies crystal field splitting of Co 3d orbitals, optimizing the spin-orbital coupling between Co 3d orbitals and iodine species.
View Article and Find Full Text PDFJ Inorg Biochem
September 2025
National Renewable Energy Laboratory, Biosciences Center, Golden, CO, USA. Electronic address:
Flavin-based electron bifurcation (FBEB) is employed by microorganisms for controlling pools of redox equivalents by reversibly splitting electron pairs into high- and low-energy levels from an initial midpoint potential. Our ability to harness this phenomenon is crucial for biocatalytic design which is limited by our understanding of energy coupling in the bifurcation system. In Pyrococcus furiosus, FBEB is carried out by the NADH-dependent ferredoxin:NADP-oxidoreductase (NfnSL), coupling the uphill reduction of ferredoxin in NfnL to the downhill reduction of NAD in NfnS from oxidation of NADPH.
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