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Reasonable nutrient and water management is effective ways to improve productivity and biodiversity of degraded grasslands. However, little is known about the effects of nutrient and water addition on soil inorganic phosphorus (P) fractions in old-field grasslands. Based on a field experiment with nutrient addition (N: 10 g·m·a, P: 10 g·m·a ) and water addition (180 mm water irrigated during plant growing season) in Duolun County, Inner Mongolia in 2005, we examined the changes of inorganic P fractions and Olsen-P contents in the topsoil (0-10 cm). Results showed that 11-year P addition significantly increased total inorganic P (TIP) content, and that exogenous P was mostly transformed into calcium phosphate (Ca-P: 62.6%-69.2%), and then into aluminium phosphate (Al-P: 19.9%-25.1%), ferric phosphate (Fe-P) and occluded P (O-P). Phosphorus incorporated with nitrogen (N) addition significantly increased Fe-P and Al-P contents by declining soil pH and activating Fe and Al in soil. Water addition alone significantly increased Fe-P, Al-P, and decalcium phosphate (Ca-P) fractions, and the contents of Fe-P, Al-P, octacalcium phosphate (Ca-P), and Ca-P were greater in P incorporated with water treatment than in P addition alone. There was no difference of each inorganic P fraction between P incorporated with N and water treatment and P incorporated with N treatment. Phosphorus and P incorporated with N additions significantly increased soil Olsen-P content, while water addition significantly decreased soil Olsen-P content under P addition alone and P incorporated with N treatment. In the calcareous soils, calcium superphosphate addition could enhance soil inorganic P pool through increasing Ca-P fraction.
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http://dx.doi.org/10.13287/j.1001-9332.202202.010 | DOI Listing |
Anal Methods
September 2025
Department of Chemistry, Faculty of Sciences, Azarbaijan Shahid Madani University, Tabriz, Iran.
This study introduces a new, highly sensitive, and reliable method for detecting and measuring orthophosphate in environmental water samples. This method combines cetyltrimethylammonium bromide (CTAB)-mediated coacervation extraction with digital image-based colorimetry, providing a robust and efficient approach for orthophosphate analysis. In this system, CTAB, a cationic surfactant, serves a dual role as both an ion-pairing agent and an extraction medium.
View Article and Find Full Text PDFAnal Methods
September 2025
Key Laboratory of Ecology of Rare and Endangered Species and Environmental Protection (Guangxi Normal University), Ministry of Education, Guilin 541004, China.
A novel magnetic nanostructured molecularly imprinted polymer probe (FeO@MIP) was developed for the continuous detection of Ti/Fe. The synthesis employed 50 nm FeO nanoparticles as the core matrix, with Ti and Fe serving as template molecules. Functional monomers α-methylacrylic acid (MAA) and acrylamide (AM) were used, along with ethylene glycol dimethacrylate (EGDMA) as the crosslinking agent and 2,2'-azobisisobutyronitrile (AIBN) as the polymerization initiator, utilizing a microwave-assisted procedure.
View Article and Find Full Text PDFChembiochem
September 2025
Department of Food, Environmental and Nutritional Sciences (DeFENS), University of Milan, via Mangiagalli 25, 20133, Milan, Italy.
This study investigates the synthesis of aromatic nitriles using an evolved variant of OxdF1 (L318F/F306Y), an aldoxime dehydratase from Pseudomonas putida F1, engineered for improved catalytic efficiency toward benzaldehyde oxime. The double OxdF1 (L318F/F306Y) mutant effectively catalyzes the conversion of various benzaldoxime derivatives to the corresponding nitriles. Due to the enzyme's inherent instability, immobilized whole-cell systems are employed in a flow reactor to improve its stability and broaden its applicability, with the biotransformation of benzaldehyde oxime and 2,6-difluorobenzaldehyde oxime serving as case studies.
View Article and Find Full Text PDFMol Nutr Food Res
September 2025
Institute of Nutritional Science, Justus-Liebig University Giessen, Giessen, Germany.
Hypertension represents a major risk factor for cardiovascular diseases. As a diet high in sodium chloride is associated with hypertension, so-called "blood pressure salts" are attracting increasing scientific interest. These are characterized by a partial replacement of sodium chloride by other salts, mainly potassium and magnesium compounds.
View Article and Find Full Text PDFMagn Reson Med
September 2025
Auckland Bioengineering Institute, The University of Auckland, Auckland, New Zealand.
Purpose: Tracer kinetic models are used in arterial spin labeling (ASL); however, deciding which model parameters to fix or fit is not always trivial. The identifiability of the resultant system of equations is useful to consider, since it will likely impact parameter uncertainty. Here, we analyze the identifiability of two-compartment models used in multi-echo (ME) blood-brain-barrier (BBB)-ASL and evaluate the reliability of the fitted water-transfer rate ).
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