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Multifunctional optical devices are desirable at all times due to their features of flexibility and high efficiency. Based on the principle that the phase of excitation light can be transferred to the generated surface plasmon polaritons (SPPs), a plasmonic grating with three functions is proposed and numerically demonstrated. The Cherenkov SPPs wake or nondiffracting SPPs Bessel beam or focusing SPPs field can be correspondingly excited for the excitation light, which is modulated by a linear gradient phase or a symmetrical phase or a spherical phase, respectively. Moreover, the features of these functions such as the propagation direction of SPPs wake, the size and direction of the SPPs Bessel beam, and the position of SPPs focus can be dynamically manipulated. In consideration of the fact that no extra fabrication is required to obtain the different SPPs fields, the proposed approach can effectively reduce the cost in practical applications.
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http://dx.doi.org/10.3390/nano11112941 | DOI Listing |
Acc Chem Res
September 2025
Department of Chemistry, FRQNT Centre for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke Street W, Montréal, Québec H3A 0B8, Canada.
ConspectusMolecular photochemistry, by harnessing the excited states of organic molecules, provides a platform fundamentally distinct from thermochemistry for generating reactive open-shell or spin-active species under mild conditions. Among its diverse applications, the resurgence of the Minisci-type reaction, a transformation historically reliant on thermally initiated radical conditions, has been fueled by modern photochemical strategies with improved efficiency and selectivity. Consequently, the photochemical Minisci-type reaction ranks among the most enabling methods for C()-H functionalizations of heteroarenes, which are of particular significance in medicinal chemistry for the rapid diversification of bioactive scaffolds.
View Article and Find Full Text PDFJ Phys Chem B
September 2025
Key Laboratory of Advanced Light Conversion Materials and Biophotonics, School of Chemistry and Life Resources, Renmin University of China, Beijing 100872, China.
Light-harvesting complex IIs (LHCIIs) are the major antenna in higher plants, balancing light capture through photoprotection. While it naturally forms trimers, stress conditions can induce monomerization, altering pigment interactions. Here, we explored how molecular oxygen affects triplet excited-state dynamics in LHCII monomers using time-resolved transient absorption spectroscopy under aerobic and anaerobic conditions.
View Article and Find Full Text PDFDalton Trans
September 2025
Department of Chemistry and Protein Research Center for Bio-Industry, Hankuk University of Foreign Studies, Yongin 17035, Republic of Korea.
The nanoscale environment within the void spaces of metal-organic frameworks (MOFs) can significantly influence the photoredox catalytic activity of encapsulated visible-light photoredox catalysts (PCs). To compare two isostructural PC@In-MOF systems, three cationic Ru(II) polypyridine complexes were successfully encapsulated within the mesoscale channels of the anionic framework of InTATB (HTATB = 4,4',4''--triazine-2,4,6-triyltribenzoic acid), which features a doubly interpenetrated framework structure. This encapsulation yielded three heterogenized visible-light PCs, RuL@InTATB, where L = 2,2'-bipyridine (bpy), 1,10-phenanthroline (phen), or 2,2'-bipyrazine (bpz).
View Article and Find Full Text PDFAdv Mater
September 2025
Instituto Interuniversitario de Investigación de Reconocimiento Molecular y Desarrollo Tecnológico, Universitat de València-Universitat Politècnica de València, Camino de Vera s/n, Valencia, 46022, Spain.
Bioorthogonal chemistry that can be controlled through near-infrared (NIR) light is a promising route to therapeutics. This study proposes a method to intracellularly photoactivate prodrugs using plasmonic gold nanostars (AuNSt) and NIR irradiation. Two strategies are followed.
View Article and Find Full Text PDFLuminescence
September 2025
Department of Physics, Saveetha Engineering College (Autonomous), Chennai, Tamilnadu, India.
The iron nickel magnesium tetra-oxide (FeNiMgO) nanocomposites (NCs) first reported in this article were synthesized using the sol-gel method. For investigation using powder X-ray diffraction (PXRD), the presence of a cubic structure is confirmed. In Raman spectroscopy, the vibrational modes are investigated.
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