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The generation of renewable energy is a promising solution to counter the rapid increase in energy consumption. Nevertheless, the availability of renewable resources (e.g., wind, solar, and tidal) is non-continuous and temporary in nature, posing new demands for the production of next-generation large-scale energy storage devices. Because of their low cost, highly abundant raw materials, high safety, and environmental friendliness, aqueous rechargeable multivalent metal-ion batteries (AMMIBs) have recently garnered immense attention. However, several challenges hamper the development of AMMIBs, including their narrow electrochemical stability, poor ion diffusion kinetics, and electrode instability. Transition metal dichalcogenides (TMDs) have been extensively investigated for applications in energy storage devices because of their distinct chemical and physical properties. The wide interlayer distance of layered TMDs is an appealing property for ion diffusion and intercalation. This review focuses on the most recent advances in TMDs as cathode materials for aqueous rechargeable batteries based on multivalent charge carriers (Zn, Mg, and Al). Through this review, the key aspects of TMD materials for high-performance AMMIBs are highlighted. Furthermore, additional suggestions and strategies for the development of improved TMDs are discussed to inspire new research directions.
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http://dx.doi.org/10.3390/nano11061517 | DOI Listing |
J Colloid Interface Sci
August 2025
College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an, Shaanxi 710054, PR China. Electronic address:
With the rapid advancement of science and technology, rechargeable aqueous zinc ion batteries (AZIBs) has garnered increasing attention in consideration of security, chemical stability and cost-effectiveness. Vanadium-based oxides have emerged as a promising high-performance electrode materials for AZIBs, owing to their high energy density, rich crystal configurations, and simple preparation process. However, the practical application of vanadium oxides is hindered by their low ion/electron transfer rate and significant capacity fading during electrochemical reactions.
View Article and Find Full Text PDFJ Phys Chem B
August 2025
CSIR-Central Glass and Ceramic Research Institute, 196 Raja S C Mullick Road, Kolkata 700032, India.
Aqueous rechargeable sodium-ion batteries (ARNIBs) are emerging as cost-effective and safe candidates for large-scale energy storage applications. However, their advancement has been constrained by the narrow electrochemical stability window (ESW) of conventional aqueous electrolytes (1.23 V).
View Article and Find Full Text PDFSmall
August 2025
CAS Key Laboratory of Mechanical Behavior and Design of Materials, Department of Modern Mechanics, CAS Center for Excellence in Complex System Mechanics, University of Science and Technology of China, Hefei, 230027, China.
Rechargeable aqueous zinc-iodine batteries (ZIBs) hold significant promise for energy storage. Their advancement, however, faces critical challenges: soluble polyiodide shuttling and rampant Zn dendrite growth. This work introduces a polyampholyte bacterial cellulose hydrogel electrolyte (SBC) engineered to overcome these limitations.
View Article and Find Full Text PDFJ Colloid Interface Sci
August 2025
School of Chemistry, Dalian University of Technology, Dalian 116024, PR China; College of Environment and Chemical Engineering, Dalian University, Dalian 116622, PR China. Electronic address:
The aqueous rechargeable magnesium ion batteries (ARMBs) are considered as one of the promising alternatives for the lithium organic batteries (Libs). However, the strong Coulombic repulsion brought by divalent alkaline earth metal ions (Mg) poses a new challenge to the stability of electrode materials. We present for the first time the introduction of a ternary medium-entropy effect (Fe, Mn and Co) at the 4b-active-site of the high spin (HS) of the Prussian blue analog (named KMEHCF) to enhance the "sp-mixing" effect of its cyanogen structure.
View Article and Find Full Text PDFACS Omega
August 2025
Department of Chemistry, Faculty of Science, Izmir Institute of Technology, Gülbahçe Campus 35430 Urla, İzmir 35050, Turkey.
Rechargeable aqueous zinc-ion batteries (AZIBs) have become a viable option in electrochemical energy storage systems (EESS) owing to their inherent safety features and economic friendliness. Nonetheless, creating suitable cathode materials for AZIBs with high structural stability, good rate performance, and great capacity remains a significant challenge. Polyoxometalate (POM)-based nanohybrid materials have shown promising results in high cycling stability and great specific capacity.
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