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In nature, ultrafast signal transfer based on ion transport, which is the foundation of biological processes, commonly works in a hydrogel-water mixed mechanism. Inspired by organisms' hydrogel-based system, we introduce hydrogel into nanofluidics to prepare a hydrogel hybrid membrane. The introduction of a space charged hydrogel improves the ion selectivity evidently. Also, a power generator based on the hydrogel hybrid membrane shows an excellent energy conversion property; a maximum power density up to 11.72 W/m is achieved at a 500-fold salinity gradient. Furthermore, the membrane shows excellent mechanical properties. These values are achievable, which indicates our membrane's huge potential applications in osmotic energy conversion.
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http://dx.doi.org/10.1021/acscentsci.0c01054 | DOI Listing |
Nat Chem
September 2025
Department of Chemistry, University of Wisconsin-Madison, Madison, WI, USA.
Proton transfer plays an important role in both hydrogen and oxygen evolution reactions during electrocatalytic water splitting to produce green hydrogen. However, directly adapting the conventional proton/deuterium kinetic isotope effect to study proton transfer in heterogeneous electrocatalytic processes is challenging. Here we propose using the shift in the Tafel slope between protic and deuteric electrolytes, or the Tafel slope isotope effect, as an effective probe of proton transfer characteristics.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Affiliated Hospital of Shandong Second Medical University, Shandong Second Medical University, Weifang, Shandong 261053, P.R. China.
Decades of antibiotic misuse have spurred an antimicrobial resistance crisis, creating an urgent demand for alternative treatment options. Although phototherapy has therapeutic potential, the efficacy of the most advanced photosensitizers (PS) is essentially limited by aggregation-induced quenching, which significantly reduces their therapeutic effect. To address these challenges, we developed a cationic metallocovalent organic framework (CRuP-COF) via a solvent-mediated dual-reaction synthesis strategy.
View Article and Find Full Text PDFBioresour Technol
September 2025
State Key Laboratory of Bioreactor Engineering and School of Chemistry and Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, PR China; Engineering Research Center of Microbial Enhanced Oil Recovery, East China University of Science and Technol
Carbon dioxide enhanced oil recovery (CO-EOR) is widely used for carbon capture, utilization, and storage in Chinese oilfields, but part of injected CO returns with produced oil, reducing carbon-reduction efficiency. Bioconverting this CO to methane energy by methanogens benefits the technology, yet on-site high-efficiency conversion meeting natural-gas grid standards remains challenging. This study used a newly-designed triple-tank bioreactor to investigate CO-to-methane conversion and methanogenic kinetics of Methanococcus maripaludis.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
WPI, International Institute for Carbon Neutral Energy Research (WPI-I2CNER), Kyushu University, Fukuoka 819-0395, Japan; Mitsui Chemicals, Inc -.Carbon Neutral Research Center (MCI-CNRC), Kyushu University, Fukuoka 819-0395, Japan. Electronic address:
This study explores highly active nitride-based g-CN/CuO photocatalysts for CO photoconversion by synthesizing them through high-pressure torsion (HPT) straining. Data indicate that increasing the applied strain under high pressure promotes vacancy formation and improves the electronic interaction at the g-CN/CuO interphases, enabling superior charge separation and extended light absorption. The generation of dual vacancies of oxygen and nitrogen is verified by electron paramagnetic resonance and Fourier transform infrared spectroscopic methods, and the generation of a type-II heterojunction is confirmed by band structure analysis.
View Article and Find Full Text PDFAnnu Rev Microbiol
September 2025
3Department of Biology, Faculty of Philosophy, Sciences and Letters at Ribeirão Preto, University of São Paulo, Ribeirão Preto, São Paulo, Brazil.
Plant biomass has emerged as a cornerstone of the global bioenergy landscape because of its abundance and cost-effectiveness. The cell wall of plant biomass is an intricate network of cellulose, hemicellulose, and lignin. The hydrolysis of cellulose and hemicellulose by holoenzymes converts these polymers into monosaccharides and paves the way for the production of bioethanol and other bio-based products.
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