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This paper focuses on the revelation of structural relationship of the ordered and disordered states in Cu-(Zr, Ti) binary systems. The atomic radial distributions in real space and the electron scattering behavior in reciprocal space between crystalline and amorphous phases are compared. The spherical-periodic order, characteristic of disordered structures, is clearly present in the crystalline phases, suggesting the structural homology of crystalline and the corresponding amorphous states. Furthermore, the diameters of Brillouin- or Jones-zones at the Fermi level in the crystalline and amorphous states are also similar and they fall close to those of the calculated Fermi spheres, verifying the resonance between the static atomic structure and the electron wave.
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http://dx.doi.org/10.1088/1361-648X/abba8b | DOI Listing |
Chem Sci
August 2025
Department of Chemistry, Indian Institute of Technology Bombay Powai Mumbai - 400076 India
The supramolecular organization of functional molecules at the mesoscopic level influences their material properties. Typically, planar π-conjugated (disc- or linear-shaped) molecules tend to undergo one-dimensional (1D) stacking, whereas two-dimensional (2D) organization from such building blocks is seldom observed in spite of their technological potential. Herein, we rationally achieve both 1D and 2D organizations from a single planar, π-conjugated molecular system competitive interactions.
View Article and Find Full Text PDFNanomicro Lett
September 2025
College of New Materials and New Energies, Shenzhen Technology University, Lantian Road 3002, Pingshan, 518118, Shenzhen, People's Republic of China.
The introduction of two-dimensional (2D) perovskite layers on top of three-dimensional (3D) perovskite films enhances the performance and stability of perovskite solar cells (PSCs). However, the electronic effect of the spacer cation and the quality of the 2D capping layer are critical factors in achieving the required results. In this study, we compared two fluorinated salts: 4-(trifluoromethyl) benzamidine hydrochloride (4TF-BA·HCl) and 4-fluorobenzamidine hydrochloride (4F-BA·HCl) to engineer the 3D/2D perovskite films.
View Article and Find Full Text PDFInt J Phytoremediation
September 2025
Department of Fashion and Textile Design, College of Arts and Design, Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.
In this paper, lignin was chemically extracted from fibers and modified with branched polyethyleneimine (BPEI) and the resulting samples were applied for the adsorption of two anionic dyes; Acid red 183 (AR183) and Acid blue 25 (AB25) from aqueous suspension. Analytical characterization methods including SEM, FT-IR, TGA/DTG, and XRD were used to analyze the studied samples. The images of the extracted lignin displayed a rough feature.
View Article and Find Full Text PDFSmall Methods
September 2025
Hebei Key Laboratory of Optic-Electronic Information and Materials, National & Local Joint Engineering Laboratory of New Energy Photoelectric Devices, College of Physics, Science and Technology, Hebei University, Baoding, 071002, China.
As a new generation of high-energy-density energy storage system, solid-state aluminum-ion batteries have attracted much attention. Nowadays polyethylene oxide (PEO)-based electrolytes have been initially applied to Lithium-ion batteries due to their flexible processing and good interfacial compatibility, their application in aluminum-ion batteries still faces problems. To overcome the limitations in aluminum-ion batteries-specifically, strong Al coordination suppressing ion dissociation, high room-temperature crystallinity, and inadequate mechanical strength-this study develops a blended polymer electrolyte (BPE) of polypropylene carbonate (PPC) and PEO.
View Article and Find Full Text PDFMagn Reson Chem
September 2025
Institute of Scientific and Industrial Research, Osaka University, Osaka, Japan.
We reveal contrasting behaviors in molecular motion between the two materials, including the identification of resonance-enhanced dynamic features in elastomers. We present a depth-resolved analysis of molecular dynamics in semicrystalline polytetrafluoroethylene (PTFE) and fully amorphous fluorinated elastomer (SIFEL) films using static-gradient solid-state F NMR imaging. By measuring spin-lattice relaxation rates ( ) at multiple frequencies and evaluating the corresponding spectral density functions, we reveal distinct dynamic behaviors between the two materials.
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