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Materials with magneto-optic coupling properties are highly coveted for their potential applications ranging from spintronics and optical switches to sensors. In this work, a new, three-phase Au-Fe-LaSrFeO (LSFO) hybrid material grown in a vertically aligned nanocomposite (VAN) form has been demonstrated. This three-phase hybrid material combines the strong ferromagnetic properties of Fe and the strong plasmonic properties of Au and the dielectric nature of the LSFO matrix. More interestingly, the immiscible Au and Fe phases form Au-encapsulated Fe nanopillars, embedded in the LSFO matrix. Multifunctionalities including anisotropic optical dielectric properties, plasmonic properties, magnetic anisotropy, and room-temperature magneto-optic Kerr effect coupling are demonstrated. The single-step growth method to grow the immiscible two-metal nanostructures (i.e., Au and Fe) in the complex hybrid material form opens exciting new potential opportunities for future three-phase VAN systems with more versatile metal selections.
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http://dx.doi.org/10.1021/acsami.0c14424 | DOI Listing |
Inorg Chem
September 2025
College of Chemistry and Materials Science, The key Laboratory of Functional Molecular Solids, Ministry of Education, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Provincial Engineering Laboratory for New-Energy Vehicle Battery Energy-Storage Materia
Conventional acid-catalyzed acetalization faces significant challenges in catalyst recovery and poses environmental concerns. Herein, we develop a CeO-supported Pd single-atom catalyst (Pd/CeO) that eliminates the reliance on liquid acids by creating a localized H-rich microenvironment through heterolytic H activation. X-ray absorption near-edge structure and extended X-ray absorption fine structure analyses confirm the atomic dispersion of Pd via Pd-O-Ce coordination, while density functional theory (DFT) calculations reveal strong metal-support interactions (SMSI) that facilitate electron transfer from CeO oxygen to Pd, downshifting the Pd d-band center and optimizing H activation.
View Article and Find Full Text PDFNano Lett
September 2025
Key Laboratory of Micro & Nano Photonic Structures, Department of Optical Science and Engineering, College of Future Information Technology, Fudan University, Shanghai 200433, China.
The separation and propagation of spin are vital to understanding spin-orbit coupling (SOC) in quantum systems. Exciton-polaritons, hybrid light-matter quasiparticles, offer a promising platform for investigating SOC in quantum fluids. By utilization of the optical anisotropy of materials, Rashba-Dresselhaus SOC (RDSOC) can be generated, enabling robust polariton spin transport.
View Article and Find Full Text PDFChemSusChem
September 2025
Institute of Organic Chemistry, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.
Organic battery electrode materials represent a sustainable alternative compared to most inorganic electrodes, yet challenges persist regarding their energy density and cycling stability. In this work, a new organic electrode material is described, which is obtained via ionothermal polymerization of low-cost starting materials, melem (2,5,8-triamino-tri-s-triazine) and perylenetetracarboxylic dianhydride (PTCDA). The resulting networked polymer Melem-PDI exhibits favorable thermal and electrochemical properties, prompting investigation into its performance as a positive electrode material in rechargeable lithium and magnesium batteries.
View Article and Find Full Text PDFAdv Mater
September 2025
Guangdong Provincial Key Laboratory of Optical Information Materials and Technology & Institute of Electronic Paper Displays, South China Academy of Advanced Optoelectronics, South China Normal University, Guangzhou, 510006, P. R. China.
Establishing a low-resistance perovskite/ITO contact using self-assembled molecules (SAMs) is crucial for efficient hole transport in perovskite solar cells (PSCs) without a pre-deposited hole-transporting layer. However, SAMs at the buried interface often encounter issues like nonuniform distribution and molecular aggregation during the extrusion process, leading to significant energy loss. Herein, a molecular hybrid bridging strategy by incorporating a novel small molecule is proposed, (2-aminothiazole-4-yl)acetic acid (ATAA), featuring a thiazole ring and carboxylic acid group, along with the commonly used SAM, 4-(2,7-dibromo-9,9-dimethylacridin-10(9H)-yl)butyl)phosphonic acid (DMAcPA), into the perovskite precursor to synergistically optimize the buried interface.
View Article and Find Full Text PDFAdv Healthc Mater
September 2025
Energy Storage Institute of Lanzhou University of Technology, School of Materials Science and Engineering, State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou, 730050, China.
The rapid advancement of implantable medical electronic devices has spurred substantial research into implantable energy storage systems. However, the presence of multiple film resistors in traditional sandwich structures impedes further enhancements in the electrochemical performance of supercapacitors and may result in contact failures between electrodes and separators or catastrophic short-circuit failures during tissue deformation. This study introduces a novel approach for fabricating all-in-one Zn-ion hybrid supercapacitors, which effectively mitigates performance degradation and safety concerns arising from interfacial issues.
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