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Metallic glasses (MGs) are promising candidates for catalysts with high efficiency for dyeing wastewater remediation, due to their metastable nature, disordered structure, and large residual stresses. However, dyeing wastewater usually contains a high concentration of inorganic ions which may have adverse effects on the degradation process, while the impacts of these ions on MGs' degradation capability have often been overlooked and still remain unknown. Thus, the roles of inorganic ions (Cl, NO, SO, and HPO) on the degradation of azo dye by Fe-based MG with nominal composition of FeSiBCu were systematically investigated. The results showed that the inorganic ions have significant influence on MG's surface morphology, degradation capability, mineralization and durability. All these aspects need to be considered prior to application of MGs for azo dyes degradation in real natural contaminated water or saline wastewater.
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http://dx.doi.org/10.1016/j.chemosphere.2020.128392 | DOI Listing |
Inorg Chem
September 2025
Department of Chemistry, Panskura Banamali College, Panskura RS, Purba Medinipur, WB 721152, India.
We report the synthesis and characterization of a new Schiff base ligand (HL), derived from 2-picolylamine and 2-hydroxy-3-methoxy-5-methylbenzaldehyde. Its reaction with Ni(NO)·6HO and Ln(NO)·HO (Ln = Gd, Tb, Dy) in the presence of triethylamine affords a carbonato-bridged family of heterobimetallic NiLn complexes: [NiLn(L)(L')(μ-CO)(NO)]·MeOH·HO (). During the complexation reaction, ligand HL undergoes an oxidation, followed by C-C coupling to generate a secondary ligand (HL').
View Article and Find Full Text PDFAdv Healthc Mater
September 2025
Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya, 466-8555, Japan.
Immune cells, such as macrophages, stimulated by several types of inorganic ions released from bioactive glasses secrete cytokines that promote and inhibit bone formation. In this study, the effects of borate-ion-stimulated mouse macrophages (RAW264) on the osteogenic differentiation of mouse bone marrow-derived mesenchymal stem cells (KUSA-A1) are investigated. KUSA-A1 is cultured with a borate-ion-containing medium and RAW264-conditioned medium, which contained the secretome released from boron-stimulated RAW264, and its osteogenic differentiation is evaluated.
View Article and Find Full Text PDFCell Mol Biol (Noisy-le-grand)
September 2025
Associate Professor, School of Pharmacy, Desh Bhagat University, Mandi Gobindgarh-Punjab 147301, India.
Alcoholic fatty liver disease (AFLD) is a leading cause of chronic liver disease worldwide, contributing to significant morbidity and mortality. Despite its growing prevalence, no FDA-approved pharmacological treatments exist, leaving lifestyle modifications as the primary intervention. AFLD pathogenesis involves a complex interplay of lipid accumulation, oxidative stress, insulin resistance, and inflammation, highlighting the need for innovative therapeutic approaches.
View Article and Find Full Text PDFACS Nano
September 2025
Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education), School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, P. R. China.
Transition metal chalcogenides (TMCs) have garnered significant attention as high-capacity anode materials, yet the unconventional role of the Cu collector meditating atomic-level substitution of metal-site cations by Cu ions during electrochemical cycling remains mechanistically unclear. To address this, herein, Cu-doped MoSe@C ultrathin nanosheets were synthesized via the solvothermal process and carbonization strategies. A systematic investigation was conducted to elucidate the underlying driving forces for Cu substitution at Mo sites and the crucial regulatory effects of solid electrolyte interphase (SEI) formation.
View Article and Find Full Text PDFDalton Trans
September 2025
Institute of Low Temperature and Structure Research, Polish Academy of Sciences, 50-422 Wroclaw, Poland.
Inorganic halide perovskites have been the subject of intensive research for their unique properties. Most current research focuses on halide ion exchange to modify the luminescence band gap and optical features. They are obtained mainly in colloids or thin layers, resulting in small grains with a narrow distribution.
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