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Article Abstract
By use of a macrocyclic phosphinite pincer ligand and bulky substrate substituents, we demonstrate how the mechanical bond can be leveraged to promote the oxidative addition of an interlocked 1,3-diyne to a rhodium(I) center. The resulting rhodium(III) bis(alkynyl) product can be trapped out by reaction with carbon monoxide or intercepted through irreversible reaction with dihydrogen, resulting in selective hydrogenolysis of the C-C σ-bond.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756736 | PMC |
| http://dx.doi.org/10.1002/anie.202009546 | DOI Listing |
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