Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
The design of metal-organic frameworks (MOFs) that incorporate more than one metal cluster constituent is a challenging task. Conventional one-pot reaction protocols require judicious selection of ligand and metal ion precursors, yet remain unpredictable. Stable, preformed nanoclusters, with ligand shells that can undergo additional coordination-driven reactions, provide a platform for assembling multi-cluster solids with precision. Herein, a discrete Co S (PTA) (PTA=1,3,5-triaza-7-phosphaadamantane) superatomic-metalloligand is assembled into a three-dimensional (3D) coordination polymer comprising Cu I secondary building units (SBUs). The resulting heterobimetallic framework (1) contains two distinct cluster constituents and bifunctional PTA linkers. Solid-state diffuse reflectance studies reveal that 1 is an optical semiconductor with a band-gap of 1.59 eV. Framework-modified electrodes exhibit reversible redox behavior in the solid state arising from the Co S superatoms, which remain intact during framework synthesis.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/chem.202001215 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Insights Into Perceived Worries Regarding the Adoption of Artificial Intelligence Among Intensive Care Unit Nurses in the West Bank.
SAGE Open Nurs
September 2025
Faculty of Allied Medical Sciences, Department of Nursing, Palestine Ahliya University, Bethlehem, Palestine.
Background: The integration of artificial intelligence (AI) into healthcare is advancing rapidly, yet little is known about how ICU nurses perceive this shift, particularly in low-resource settings.
Objectives: This study aimed to examine ICU nurses' perceived concerns regarding AI adoption, focusing on awareness, prior experience, and levels of worry related to AI integration.
Methods: A cross-sectional survey was conducted among 235 ICU nurses from nine hospitals in the West Bank.
If you build it, they will come - Implementation of a prehospital whole blood program.
Am J Surg
August 2025
Emory University School of Medicine, USA; Grady Health System, USA. Electronic address:
Introduction: We sought to develop, implement and evaluate an urban prehospital whole blood (PH-WB) program.
Methods: Using retrospective heat map data, Quick Response Vehicles (QRVs) carrying PH-WB were strategically placed throughout the city and dispatched using dynamic deployment. Patient inclusion criteria were age ≥15 years, traumatic mechanism, and SBP ≤90 mmHg.
Preparation of ketonyl -glycosides from designed glycosyl sulfides and styrenes by a radical pathway.
Sci Adv
September 2025
Department of Pulmonary and Critical Care Medicine, Targeted Tracer Research and Development Laboratory, Institute of Respiratory Health, Frontiers Science Center for Disease-related Molecular Network, State Key Laboratory of Respiratory Health and Multimorbidity, Institute of Respiratory Health and
Ketonyl -glycosides, a vital subclass of alkyl -glycosides, play essential roles in drug discovery, biochemistry, and materials sciences. However, a practical strategy that merges bench-stable glycosyl donors with styrenes-a ubiquitous class of synthetic building blocks-remains elusive. Herein, we report a simple and general approach for synthesizing ketonyl -glycosides.
View Article and Find Full Text PDFHow big is the medical writing industry? Why it matters.
Health Promot Int
September 2025
Department of Philosophy, Queen's University, Kingston, ON, K7L 3N6, Canada.
Medical writing is a key element in pharmaceutical companies' efforts to shape the relevant medical science literature. As part of what is called 'publication planning', medical writing can influence the knowledge base on which prescribers make decisions, and can build specific claims in targeted sales efforts. Most publication planning is done by hired medical education and communication companies (MECCs), with the rest done by other commercial entities, such as units of pharmaceutical companies or of contract research organizations, that provide essentially the same services as MECCs.
View Article and Find Full Text PDFAssociation Between School Neighborhood Walkability and Adolescent Physical Activity.
J Healthy Eat Act Living
June 2025
Department of Population Health Sciences, Duke University School of Medicine, U.S.A.
Neighborhood structural factors are associated with greater feasibility of youth active travel and thus, greater levels of physical activity. However, limited prior work has addressed walkability factors specific to the school neighborhood related to adolescent physical activity during the school day. Therefore, the purpose of this study was to examine the relationship between two school neighborhood walkability factors (neighborhood density and neighborhood age) and school-related adolescent moderate-to-vigorous physical activity (MVPA).
View Article and Find Full Text PDF