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The effect of biochar on the bulk density and aggregate stability of Lou soil was evaluated and compared after biochar was applied for 2 years and 5 years through a field-positioning experiment. Five biochar amounts were applied in this study, as follows:0 t·hm (B), 20 t·hm (B), 40 t·hm (B), 60 t·hm (B), and 80 t·hm (B). The biochar was produced by pyrolysis of stems and branches from fruit trees at the temperature of 450℃ with limited oxygen apply. At the beginning of the study, biochar was mixed thoroughly with the surface soil (0-20 cm). After 5 years, the soil bulk density and aggregate stability of 0-30 cm soil layers (0-10, 10-20, and 20-30 cm) were measured and compared with the results obtained after 2 years with the purpose of observing the long-term and persist effects of biochar application. The results showed that:① compared with the results after 2 years of application, the effect of biochar on the aggregates at depths of 0-10 cm and 10-20 cm after 5 years were less distinct, and the effect on soil aggregates at depths of 20-30 cm was significantly enhanced; ② compared with the 2 year application, the aggregate stability and the content of the>0.25 mm aggregate size fraction were significantly increased at 0-10 cm depths after 5 years of biochar application at a rate of 40 t·hm, while bulk density was significantly decreased; at 10-20 cm and 20-30 cm soil depths, the stability of aggregates and the content of the>0.25 mm aggregate size fraction was significantly increased, while the bulk density was significantly decreased after 5 years of biochar application at a rate of 60-80 t·hm;③ when the biochar application rate was 60 t·hm, the increase in soil organic carbon was the highest after 5 years. After biochar was applied for 5 years, its effect was more significant lower in the soil profile; the soil bulk density was significantly reduced, and aggregate stability and the content of>0.25 mm aggregates were significantly increased at depths of 20-30 cm. Based on a comprehensive evaluation of the improvement effects and economic benefits, the most suitable biochar application rate was found to be 40-60 t·hm. It was further concluded that the effect of biochar on soil aggregates was gradual and sustainable.
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http://dx.doi.org/10.13227/j.hjkx.201808094 | DOI Listing |
Environ Technol
September 2025
College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, People's Republic of China.
The soil in reclaimed shale gas sites is compacted and suffers from issues like poor drainage, drought conditions, and nutrient deficiency, posing challenges for agricultural production. In this study, rare earth tailings were incorporated into biochar at different mass ratios (rare earth tailings: biochar = 1:1, 1:2, 1:3, 1:4). Subsequently, a series of rare earth tailings-doped biochar materials (REE-BC) were prepared by calcination at 700°C.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2025
Department of Earth System Sciences, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, Republic of Korea.
We present a systematic high-pressure investigation of the chlorine-functionalized two-dimensional hybrid perovskite (ClPMA)PbI, integrating high-pressure synchrotron powder X-ray diffraction (HP-PXRD), photoluminescence spectroscopy (HP-PL), and first-principles density functional theory (DFT) calculations. Under hydrostatic compression up to 6.18 (±0.
View Article and Find Full Text PDFSmall
September 2025
Smart Material Research Laboratory, Department of Physics, Indian Institute of Technology Roorkee, Roorkee, 247667, India.
Achieving superior energy storage performance in dielectric materials under low electric fields remains a challenge. Most recent advancements require high fields that limit device applicability. Developing dielectric capacitors with high recoverable energy density (W), efficiency (η), and energy-storage coefficient (W/E) at low/moderate fields is critical for safer, compact, and durable electronics.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
September 2025
Departamento de Física Aplicada - Instituto de Ciencia de Materiales, Matter at High Pressure (MALTA) Consolider Team, Universidad de Valencia, Edificio de Investigación, C/Dr Moliner 50, 46100 Burjassot, Valencia Spain.
The effects of pressure on the crystal structure of scheelite-type perrhenates were studied using synchrotron powder X-ray diffraction and density-functional theory. At ambient conditions, the studied materials AgReO, KReO, and RbReO, exhibit a tetragonal scheelite-type crystal structure described by space group 4/. Under compression, a transition from scheelite-to-M'-fergusonite (space group 2/) was observed at 1.
View Article and Find Full Text PDFNanoscale Horiz
September 2025
Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, USA.
Nanostructuring, which shortens lithium-ion diffusion lengths, can help facilitate pseudocapacitive behavior in some battery materials. Here, nanostructured LiNiCoAlO (NCA), with porosity and decreased crystallite size compared to commercial bulk NCA, was synthesized using a colloidal polymer template. Small particles (∼150 nm) were obtained using rapid thermal annealing (RTA), while medium particles (∼300 nm) were obtained with conventional heating.
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