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Gasification and pyrolysis have been considered as potential routes for the production of fuel gas from abundant, low-cost and renewable biomass materials. Tar is the undesirable but inevitable byproduct during these processes, which not only lowers the overall energy conversion efficiency but also leads to potential contamination and clogging problems. Catalytic reforming has been seen as one of the most promising methods for tar elimination, and biochar-based nanocatalysts (BBNs) show promise as an efficient tar reforming catalyst. Extensive research efforts have been devoted to the development of BBNs to reduce biomass tar below tolerable limits. This current study reviews the recent progress in the preparation and application of BBNs for converting tar into fuel gas during biomass gasification or pyrolysis. The formation and chemical characteristics of the BBNs are introduced for a better understanding of the catalytic mechanism; prospects for success, as well as challenges, are also discussed.
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http://dx.doi.org/10.1016/j.biortech.2019.122263 | DOI Listing |
Environ Sci Pollut Res Int
January 2025
Department of Chemistry, National Institute of Technology, Silchar, 788010, Assam, India.
In this work, Terminalia chebula leaf extract was used to synthesize CuO-CoO nanoparticles, which were then embedded in a rice straw biochar. This new biochar-based nano-catalyst is used to photocatalytically degrade a variety of dyes (Eosin Y, Trypan Blue, Crystal Violet, Methylene Blue, Brilliant Green), as well as a binary mixture of Eosin Y and Trypan Blue dyes. It is also used for the catalytic reduction of nitro compounds (4-NP, 3-NP, and Picric acid).
View Article and Find Full Text PDFBioresour Technol
July 2023
State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, PR China. Electronic address:
Nanocatalysts are beneficial for tar elimination and syngas production during biomass gasification. In this study, novel biochar-based nanocatalysts loaded with Ni/Ca/Fe nanoparticles was prepared by one-step impregnation method for catalytic steam gasification of biomass. Results showed that the metal particles were evenly distributed with the particle size of less than 20 nm.
View Article and Find Full Text PDFBioresour Technol
February 2020
Center for Biorefining, Bioproducts and Biosystems Engineering Department, University of Minnesota, St. Paul, MN 55108, United States. Electronic address:
Gasification and pyrolysis have been considered as potential routes for the production of fuel gas from abundant, low-cost and renewable biomass materials. Tar is the undesirable but inevitable byproduct during these processes, which not only lowers the overall energy conversion efficiency but also leads to potential contamination and clogging problems. Catalytic reforming has been seen as one of the most promising methods for tar elimination, and biochar-based nanocatalysts (BBNs) show promise as an efficient tar reforming catalyst.
View Article and Find Full Text PDF