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This study aims to investigate the combination of speckle pattern analysis, polarization parameters, and chemometric tools to predict the optical absorption and scattering properties of materials. For this purpose, an optical setup based on light polarization and speckle measurements was developed, and turbid samples were measured at 405 and 660 nm. First, a backscattered polarized speckle acquisition was performed on a set of 41 samples with various scattering (${\mu}_s$μ) and absorbing (${{\mu}_a}$μ) coefficients. Then, several parameters were computed from the polarized speckle images, and prediction models were built using stepwise multiple linear regression. For scattering media, ${{\mu}_s}$μ was predicted with ${R^{2} = 0.9}$R=0.9 using two parameters. In the case of scattering and absorbing media, prediction results using two parameters were ${R^{2} = 0.62}$R=0.62 for ${{\mu}_s}$μ and ${R^{2} = 0.8}$R=0.8 for ${{\mu}_a}$μ. The overall results obtained in this research showed that the combination of speckle pattern analysis, polarization parameters, and chemometric tools to predict the optical bulk properties of materials show interesting promise.
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http://dx.doi.org/10.1364/AO.58.008247 | DOI Listing |
J Am Chem Soc
September 2025
State Key Laboratory of Chemistry for NBC Hazards Protection, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China.
The activation of methane and other gaseous hydrocarbons at low temperature remains a substantial challenge for the chemistry community. Here, we report an anaerobic photosystem based on crystalline borocarbonitride (BCN) supported Fe-O nanoclusters, which can selectively functionalize C-H bonds of methane, ethane, and higher alkanes to value-added organic chemicals at 12 °C. Scanning transmission electron microscopy and X-ray absorption spectroscopy corroborated the ultrafine FeOOH and FeO species in Fe-O clusters, which enhanced the interfacial charge transfer/separation of BCN as well as the chemisorption of methane.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
September 2025
Department of Bioengineering, Stanford University, Stanford, CA 94305.
Despite periods of permanent darkness and extensive ice coverage in polar environments, photosynthetic ice diatoms display a remarkable capability of living inside the ice matrix. How these organisms navigate such hostile conditions with limited light and extreme cold remains unknown. Using a custom subzero temperature microscope during an Arctic expedition, we present the finding of motility at record-low temperatures in a Eukaryotic cell.
View Article and Find Full Text PDFInorg Chem
September 2025
Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research, Key Laboratory of Light Energy Conversion Materials of Hunan Province College, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, P. R. China.
The super bulky sodium phosphanide, NaP(SiPr), was reacted with amidinatotetrylenes LECl (L = PhC(NBu), E = Si, Ge), resulting in the formation of phosphasilene LSi(SiPr) = PSiPr () and phosphanido germylene LGeP(SiPr) (), respectively. Investigation on the reactivity of and toward elemental sulfur was carried out, where a stepwise reaction yielding the silanethione LSi(=S)SiPr () and the silicon thioester analogue LSi(=S)SSiPr () was observed in the case of , while the treatment of with sulfur exclusively afforded the germanium thioester analogue. In addition, the reactions of with Fe(CO) and GeCl·1,4-dioxane led to the germylene-coordinated iron carbonyl and the asymmetric Ge-Ge-bonded complex, respectively, exhibiting the reactivity of the lone pair as well as a weak Ge-P bond.
View Article and Find Full Text PDFPlant Biotechnol J
September 2025
College of Agronomy, Key Laboratory of High-Efficiency Production of Wheat-Maize Double Cropping, Henan Agricultural University, Zhengzhou, China.
The magnetic field is a continuously present environmental factor. It has been found that many species, including plants, can sense and utilise it. However, the effects of the magnetic field on plants and its potential utilisation, especially in crops, have been little explored.
View Article and Find Full Text PDFJ Sci Food Agric
September 2025
Department of Food Science and Engineering, Institute of Food Safety and Nutrition, Jinan University, Guangzhou, People's Republic of China.
Background: Blood orange peels represent an underutilized source of high-value flavonoids with broad bioactivities. Traditional single-extraction techniques for citrus flavonoids suffer from low efficiency due to polarity limitations, significantly restricting their industrial-scale development and application. As a result, there is an urgent need to develop green and efficient extraction processes to improve both the coverage and yield of citrus flavonoids.
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