Reduction of steel slag leachate pH via humidification using water and aqueous reagents.

A slag humidification process that aims to reduce the leachate pH of steel slag via carbonation was accomplished by simply wetting the slag and exposing it to the atmosphere for passive diffusion of atmospheric CO. The optimization parameters of the process were studied. Results showed that by wetting the slag using various aqueous solutions (deionized water, NaCl solution and NaOH solution), such that its moisture content nearly reaches its water holding capacity, a significant reduction in leachate pH could be achieved. Pretreatment of the slag using 1 M NaOH and subsequent humidification using deionized water showed the best efficiency of 1.1 pH unit reduction among the tested conditions. Slag pretreatment could substantially enhance the carbonation degree on the slag surface, leading to conservation of the treatment effectiveness up to three times the leachate replenishment using deionized water. The benefit of the alkaline treatment to promote slag carbonation could also be achieved using a low to moderate (0.005-0.1 M) NaOH solutions for humidification without the pretreatment step. A 72.5% increase in the treatment efficiency could be achieved via a humidification treatment using 0.005 M NaOH solution compared to that using deionized water. This study shows the promise of humidification treatment as a low-cost, easily implemented, and environmentally friendly slag pH neutralization process that can be applied in the field for slag treatment prior to its use or disposal in the environment.