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We report the observation of ferromagnetic (FM) and antiferromagnetic (AFM) interlayer exchange coupling (IEC) in GaMnAsP-based trilayer structures with out-of-plane magnetic anisotropy. Magnetization and anomalous Hall effect (AHE) measurements show well-resolved magnetization transitions corresponding to the two GaMnAsP layers. Minor loop measurements reveal a characteristic shift caused by IEC in all trilayer samples investigated. Interestingly, the FM IEC changes to AFM IEC for a trilayer with the thinnest (7 nm) top GaMnAsP layer as the temperature increases. The observation of temperature-induced transition of FM and AFM IEC in the same sample suggests the possibility of device applications by controlling the type of IEC in such GaMnAsP-based multilayers.
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http://dx.doi.org/10.1038/s41598-019-41138-9 | DOI Listing |
Environ Res
September 2025
School of Resources and Environment, Northeast Agricultural University, Harbin, 150030, China; School of Ecology and Environment, Hainan University, Haikou 570228, China. Electronic address:
Herein, ball-milled magnetic biochar-vermiculite composite (MBC@VT) and ball-milled magnetic biochar-zeolite composite (MBC@ZT) were synthesized via one-step ball-milling, and their adsorption capacities for Pb(II)/P-nitrophenol (PNP) in water were compared. The results demonstrated that the removal of Pb(II) and PNP through both materials was a complex, endothermic reaction mainly driven by chemisorption, with strong tolerance to pH changes and co-existing ions. MBC@VT showed superior adsorption for Pb(II) (reaching 367.
View Article and Find Full Text PDFSci Adv
September 2025
National Laboratory of Solid State Microstructures, School of Electronic Science and Engineering and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China.
Two-dimensional (2D) materials offer strong light-matter interaction and design flexibility beyond bulk semiconductors, but an intrinsic limit is the low absorption imposed by the atomic thickness. A long-sought-after goal is to achieve complementary absorption enhancement through energy transfer (ET) to break this limit. However, it is found challenging due to the competing charge transfer (CT) process and lack of resonance in exciton states.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.
Layered van der Waals (vdW) materials, characterized by their interlayer vdW gaps, offer exceptional tunability of magnetic properties via intercalation chemistry. A wide range of magnetic behaviors have been observed in nonmagnetic transition-metal dichalcogenides intercalated with magnetic atoms. Beyond the incorporation of magnetic ions, we propose the controlled alkali-ion intercalation of intrinsic vdW magnets as a strategy to probe and manipulate spin populations and exchange interactions within individual magnetic layers.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
TOSOH SGM Corp., 4555, Kaisei-cho, Shunan, Yamaguchi 746-0006, Japan.
This study presents a simple method for embedding inorganic-organic hybrid lead halide perovskite (CHNH)PbX (X = Cl, Br, or I) nanocrystals (NCs) into the interlayer spaces of the layered polysilicate kenyaite. (CHNH)PbX NC-embedded kenyaite composites (MPX@kenyaite) were synthesized by immersing Pb-containing kenyaite in (CHNH)X-containing 2-propanol. According to X-ray diffraction, small-angle X-ray scattering, and scanning transmission electron microscopy analyses, (CHNH)PbX NCs with diameters of 5.
View Article and Find Full Text PDFAdv Sci (Weinh)
September 2025
Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai, 201204, P. R. China.
Ferrimagnets (FiMs), particularly compensated FiMs, composing of coupled sublattices with antiparallel and inequivalent magnetic moments, present a unique material platform for the regulation of magnetism, which is highly desirable for the design of next-generation spin-based devices. Nevertheless, highly efficient methods for controlling its ferromagnetism remains significantly limited owning to the epitaxial growth required for producing high quality and fully featured films. This study, demonstrates the multiple tunability of ferrimagnetism in the rare-earth iron garnets (REIG: thulium iron garnet) film by incorpoating the graphene interlayers.
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