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A Chitosan/triethanolamine/Cu (Ⅱ) (CTS/TEA/Cu (Ⅱ)) composite adsorbent was prepared and applied to recycle Cr (Ⅵ) from aqueous media in alkaline conditions. To investigate the adsorption behavior, the influence of pH was evaluated via batch experiments, and the prepared adsorbent was characterized by FT-IR, SEM, XRD, and Zeta potential. This adsorbent exhibited high adsorption capacity for Cr (Ⅵ) in a wide pH range (especially above 7), suggesting a possible way to separate Cr (Ⅵ) from other metal cations by adjusting the pH value prior to adsorption. Adsorption kinetic and thermodynamic experiments were conducted to explore the adsorption mechanism. Regeneration studies showed that the adsorbent can be reused for five adsorption-desorption cycles without substantial loss of adsorption capacity. Overall, the CTS/TEA/Cu (Ⅱ) adsorbent exhibits high potential for recyclingCr (Ⅵ) from wastewater.
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http://dx.doi.org/10.1016/j.carbpol.2018.10.004 | DOI Listing |
Inorg Chem
September 2025
Pacific Northwest National Laboratory, Richland, Washington 99352, United States.
The solvation structure of an Np ion in an aqueous, noncomplexing and nonoxidizing environment of trifluoromethanesulfonic (triflic) acid was investigated with X-ray absorption spectroscopy (XAS) combined with ab initio molecular dynamics (AIMD) and time-dependent density functional theory (TDDFT) calculations. Np L-edge X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) data were collected for Np in 1, 3, and 7 M triflic acid using a laboratory-scale spectrometer and separately at a synchrotron facility, producing data sets in excellent agreement. TDDFT calculations revealed a weak pre-edge feature not previously reported for Np L-edge XANES.
View Article and Find Full Text PDFNatl Sci Rev
September 2025
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, China.
Precision in controlling the microenvironment of nanospaces is a potent strategy for exploring architecture‒function relationships. Herein, a face-capped tetrahedral cage, featuring Pd‒Pd-bonded vertices, with a tailored nanospace surrounded by 12 ethyl units, was facilitated to adaptively accommodate a library of guests with different sizes and shapes, including C6 cyclic hydrocarbons, adamantane derivatives, S and P. This nanocavity can achieve strong binding with cyclohexane in non-aqueous media in contrast to reported structurally similar non--functionalized cages by an increase of four orders of magnitude.
View Article and Find Full Text PDFSoft Matter
September 2025
Nestlé Product Technology Centre, York, YO31 8FY, UK.
Particles with some degree of hydrophilicity are known to aggregate when directly dispersed in non-aqueous media. Proteins are generally insoluble in oil and have complex surface properties, but they may form networks in oil like more simple colloidal particles, depending on particle size and surface hydrophilicity. Here, the particle size of pea protein isolate (PPI) particles in oil was reduced to submicron sizes by stirred media milling.
View Article and Find Full Text PDFLangmuir
September 2025
Institute of Technology for Carbon Neutralization, Yangzhou University, Yangzhou 225127, Jiangsu, China.
To expand the application scope of carbon steel, imparting superhydrophobicity to its surface offers an effective strategy to overcome its inherently poor corrosion resistance. However, in marine environments, conventional superhydrophobic coatings often suffer from limited mechanical durability and inadequate long-term corrosion protection. In this study, a durable superhydrophobic bilayer coating composed of PDMS-MWCNTs (top layer) and PDMS (bottom layer) was developed to address these challenges.
View Article and Find Full Text PDFLight Sci Appl
September 2025
Department of Chemistry, State Key Laboratory of Molecular Engineering of Polymers, Laboratory of Advanced Materials, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials and iChem, Fudan University, Shanghai, 200433, China.
Conventional optical probes suffer from signal degradation in aqueous media, hindering sensitive biodetection. To overcome this, newly developed water-insensitive down-shifting nanoparticles (WINPs) possess superior photophysical properties in the NIR-I window, including high quantum yield and negligible thermal effects, permitting stable, high-contrast signal generation under low excitation power. This advantage facilitated a low-power lateral flow assay capable of highly sensitive avian influenza virus (AIV) detection in the opaque biological matrices (such as avian swabs), mitigating interference issues relying on visible-range signals.
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