[Distribution Characteristics and Release Fluxes of Phosphorus Forms in Xiangxi Bay Sediments in the Three Gorges Reservoir Before and After Impoundment].

The sediment storage environment in tributaries has been altered by impoundment of water in the Three Gorges Reservoir area, affecting the distribution of phosphorus forms in sediment and processes at the sediment-water interface. Through collection of sediment and overlying water samples in Xiangxi Bay in August 2016 (before impoundment) and October (after impoundment), the distribution characteristics of sedimentary phosphorus and the environmental conditions of storage before and after impoundment were analyzed. Fluxes of PO-P at the sediment-water interface were also estimated. Results show that pH increased, alkalinity and reducibility were enhanced, and Eh in sediments decreased after impoundment. The relative content of phosphorus in sediments changed as follows:NaOH-P > HCl-P > OP to HCl-P > OP > NaOH-P; this could be attributed to changes in the depositional environment. Compared to pre-impoundment values, TP values after impoundment in sediment, overlying water (PO-P), and interstitial water (PO-P) were 1.3 times, 3.7 times, and 8.3 times higher, increasing the risk of nutrient release in sediments of Xiangxi Bay. The manifestation of PO-P in sendiments of Xiangxi River generally is "source" pre-impoundment and post-impoundment, but the PO-P diffusive flux increased from -0.0029-0.0059 mg·(m·d) pre-impoundment to 0.0067-0.1071 mg·(m·d) post-impoundment. The release of phosphorus from sediments at the bottom of Xiangxi Bay increased after impoundment.