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Active matrix organic light-emitting diodes (AMOLEDs) are considered to be a core component of next-generation display technology, which can be used for wearable and flexible devices. Reliable thin-film transistors (TFTs) with high mobility are required to drive AMOLEDs. Recently, amorphous oxide TFTs, due to their high mobility, have been considered as excellent substitutes for driving AMOLEDs. However, the device instabilities of high-mobility oxide TFTs have remained a key issue to be used in production. In this paper, we present the charge-trapping and device instability mechanisms of high-mobility oxide TFTs with double active layers, using In-Zn-O (IZO) and Al-doped Sn-Zn-In-O (ATZIO) with various interfacial IZO thicknesses (0-6 nm). To this end, we employed microsecond fast current-voltage (I-V), single-pulsed I-V, transient current, and discharge current analysis. These alternating-current device characterization methodologies enable the extraction of various trap parameters and defect densities as well as the understanding of dynamic charge transport in double-active-layer TFTs. The results show that the number of defect sites decreases with an increase in the interfacial IZO thickness. From these results, we conclude that the interfacial IZO layer plays a crucial role in minimizing charge trapping in ATZIO TFTs.
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http://dx.doi.org/10.1021/acsami.7b01533 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
Department of Material Sciences and Engineering, Seoul National University, Seoul 08826, Republic of Korea.
A nanometer-scale multilayer gate insulator (GI) engineering strategy is introduced to simultaneously enhance the on-current and bias stability of amorphous InGaZnO thin-film transistors (a-IGZO TFTs). Atomic layer deposition supercycle modifications employ alternating layers of AlO, TiO, and SiO to optimize the gate-oxide stack. Each GI material is strategically selected for complementary functionalities: AlO improves the interfacial quality at both the GI/semiconductor and GI/metal interfaces, thereby enhancing device stability and performance; TiO increases the overall dielectric constant; and SiO suppresses leakage current by serving as a high-energy barrier between AlO and TiO.
View Article and Find Full Text PDFNanomaterials (Basel)
August 2025
Department of Semiconductor Engineering, Gachon University, Seongnam City 13120, Republic of Korea.
Amorphous indium gallium zinc oxide (a-IGZO) is widely used as an oxide semiconductor in the electronics industry due to its low leakage current and high field-effect mobility. However, a-IGZO suffers from notable limitations, including crystallization at temperatures above 600 °C and the high cost of indium. To address these issues, nitrogen-doped zinc oxynitride (ZnON), which can be processed at room temperature, has been proposed.
View Article and Find Full Text PDFACS Appl Mater Interfaces
August 2025
Department of Electronic Engineering, Hanyang University, Seoul 04763, Republic of Korea.
This study demonstrates that IGZO compositions with low-indium (In) content can undergo effective crystallization via a low-temperature route. The IGZO films were initially thermally annealed at 400 °C to enhance structural quality, followed by titanium (Ti) metal-induced crystallization (MIC) at 300 °C under ambient oxygen conditions. Systematically varying the zinc (Zn) content in the IGZO channel while maintaining a fixed indium-to-gallium ratio revealed the relationship between microstructural evolution and electrical performance/stability.
View Article and Find Full Text PDFACS Appl Mater Interfaces
August 2025
Department of Electrical and Computer Engineering, University of California San Diego, 9500 Gilman Dr., La Jolla, California 92093, United States.
The development of ultrathin amorphous indium-gallium-zinc oxide (a-IGZO) thin-film transistor (TFT) technology, capable of delivering high mobility and robust device reliability, is essential for next-generation oxide-TFT applications such as 3D monolithic highly integrated circuits. While using In-rich a-IGZO channels is a straightforward strategy to enhance device mobility, it causes serious TFT instability due to the increase in the weakly bonded In-O. Therefore, overcoming the trade-off between mobility and stability is critical for the advancement of oxide-TFT technology.
View Article and Find Full Text PDFACS Appl Mater Interfaces
August 2025
School of Advanced Materials Science and Engineering, Sungkyunkwan University, 2066 Seobu-ro, Jangan-gu, Suwon-si, Gyeonggi-do 16419, Republic of Korea.
A critical challenge in flexible high-performance thin-film transistors (TFTs) is ensuring the reliability of the dielectric layer with a high-mobility semiconductor, which must maintain its insulating properties while withstanding repeated mechanical deformation. In this study, we investigate photo-cross-linkable photosensitive polyimide (PSPI), 4,4'-(hexafluoroisopropylidene)diphthalic anhydride-3,5-diaminobenzyl cinnamate (6FDA/DABC), as a dielectric material in oxide TFTs using zinc tin oxide or indium gallium zinc oxide as the channel materials. The photo-cross-linked PSPI dielectric exhibited a high areal capacitance of 17.
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