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We demonstrate the refinement and uniform distribution of the crystalline dendritic phase by friction stir processing (FSP) of titanium based ductile-phase reinforced metallic glass composite. The average size of the dendrites was reduced by almost a factor of five (from 24 m to 5 m) for the highest tool rotational speed of 900 rpm. The large inter-connected dendrites become more fragmented with increased circularity after processing. The changes in thermal characteristics were measured by differential scanning calorimetry. The reduction in crystallization enthalpy after processing suggests partial devitrification due to the high strain plastic deformation. FSP resulted in increased hardness and modulus for both the amorphous matrix and the crystalline phase. This is explained by interaction of shear bands in amorphous matrix with the strain-hardened dendritic phase. Our approach offers a new strategy for microstructural design in metallic glass composites.
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http://dx.doi.org/10.1088/1468-6996/15/3/035011 | DOI Listing |
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September 2025
College of Environment and Climate, Jinan University, Guangzhou, 511443, China.
Membrane technology for gas separation is more efficient and energy-saving than thermally driven processes, including cryogenic distillation and adsorption. Metal-organic framework (MOF) and related glass membranes hold great potential for precise gas separation, but it remains challenging to construct ultrathin MOF glass membranes and optimize their transport pathways. In this study, a strategy based on vapor-linker deposition and melt-quenching is reported to design ultrathin zeolitic imidazolate framework (ZIF) glass membranes with node-missing defect passageways.
View Article and Find Full Text PDFJ Chem Phys
September 2025
August Chełkowski Institute of Physics, University of Silesia in Katowice, 75 Pułku Piechoty 1, 41-500 Chorzów, Poland.
In this paper, we investigated the thermal, dynamical, and structural properties, as well as association patterns, in 3-phenyl-1-propanol (3P1Pol) and 3-phenyl-1-propanal (3P1Pal), with special attention paid to the latter compound. Both systems turned out to be good glass formers, differing by 17 K in the glass transition temperature, which indicated a strong change in the self-assembly pattern. This supposition was further confirmed by the analysis of dielectric spectra, where, apart from the α-relaxation, also a unique Debye (D)-mode, being a fingerprint of the self-association, characterized by different dynamical properties (dielectric strength, timescale separation from the α-process), was detected in both samples.
View Article and Find Full Text PDFAnal Sci
September 2025
Frontier Laboratories Ltd., 4-16-20, Saikon, Koriyama, Fukushima, 963-8862, Japan.
Biomass-based polymers such as poly(lactic acid) (PLA) have attracted much attention, because they are renewable, biocompatible, and nontoxic to the environment and have been used in various fields such as biomedical, agricultural, and food packaging industries. However, one of the common drawbacks of PLA-based materials is their low glass transition temperature in the amorphous state, while adding phenylphosphonic acid zinc salt (PPA-Zn) as a nucleating agent was found to be a promising method to improve the physical property of PLA. On the other hand, degradation of PLA-based materials in the environment may cause the pollution from the metal of a nucleating agent in PLA and quantification of nucleating agents in polymers is of interest.
View Article and Find Full Text PDFPLoS One
September 2025
School of Nuclear Science and Technology, University of South China Hengyang, Hunan, China.
With the rapid development of the nuclear medicine business worldwide, the removal of iodine-131 from specific contaminated environments to protect public health has important application prospects. In this study, the surface decontamination mechanism of Ce(IV)/HNO3 as a decontaminant for iodine-131-contaminated nonmetallic materials was investigated by using an orthogonal experimental method and scanning electron microscopy (SEM). During the preparation experiments with the contaminated materials, both quartz glass and ceramics reached peak activity concentration levels at 4 h of adsorption (contamination) by using immersion; the decontamination factor (DF) was selected as the test index for the decontamination experiments.
View Article and Find Full Text PDFACS Omega
September 2025
School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, United Kingdom.
The present research reports the synthesis of poly-[ethylene oxide]-based composite films (500 μm) containing metal nanoparticles (NPs) [Ag ( ∼ 6 nm), Cu ( ∼ 25 nm), and Fe ( ∼ 35 nm)] as the mobile phase. The novelty of the study is in the corroboration of a plausible mechanism for the generation of metal NPs through green synthesis using herbal extracts of (Tea) and (Neem). Density functional theory (DFT) is used to optimize the phytoreductants present in both biosources, wherein the reducing and/or stabilizing functional entities are primarily hydroxyl groups (-OH).
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