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The absorption of ultraintense, femtosecond laser pulses by a solid unleashes relativistic electrons, thereby creating a regime of relativistic optics. This has enabled exciting applications of relativistic particle beams and coherent X-ray radiation, and fundamental leaps in high energy density science and laboratory astrophysics. Obviously, central to these possibilities lies the basic problem of understanding and if possible, manipulating laser absorption. Surprisingly, the absorption of intense light largely remains an open question, despite the extensive variations in target and laser pulse structures. Moreover, there are only few experimental measurements of laser absorption carried out under very limited parameter ranges. Here we present an extensive investigation of absorption of intense 30 femtosecond laser pulses by solid metal targets. The study, performed under varying laser intensity and contrast ratio over four orders of magnitude, reveals a significant and non-intuitive dependence on these parameters. For contrast ratio of 10(-9) and intensity of 2 × 10(19)W cm(-2), three observations are revealed: preferential acceleration of electrons along the laser axis, a ponderomotive scaling of electron temperature, and red shifting of emitted second-harmonic. These point towards the role of J × B absorption mechanism at relativistic intensity. The experimental results are supported by particle-in-cell simulations.
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http://dx.doi.org/10.1038/srep17870 | DOI Listing |
Int J Biol Macromol
September 2025
College of Textiles, Donghua University, Shanghai, 201620, China; Key Laboratory of Textile Science & Technology, Ministry of Education, Donghua University, Shanghai, 201620, China. Electronic address:
In this study, a novel bleaching method for ramie cellulose fibers with low oxidative damage was developed by utilizing the properties of sodium percarbonate contained in tea saponin, which slowly releases hydrogen peroxide in the catalytic oxidation system of N-hydroxyphthalimide (NHPI). First, the bleaching process was optimized using response surface design, followed by comparison and characterization of fiber properties prepared under different bleaching systems. Finally, the energy consumption, water consumption, and toxicity of the NHPI/tea saponin system were evaluated.
View Article and Find Full Text PDFLangmuir
September 2025
Federal University of São Paulo, Laboratory of Hybrid Materials, Diadema, São Paulo 09913-030, Brazil.
This study demonstrates the successful fabrication of nanostructured Langmuir-Blodgett (LB) films combining the conjugated copolymer poly(9,9-dioctylfluorene--3,4-ethylenedioxythiophene) (PDOF--PEDOT) with spherical and triangular silver nanoparticles (AgNP). The LB technique allowed precise control over the molecular arrangement and distribution of the nanoparticles at the air-water interface, resulting in compact, reproducible and structurally ordered nanocomposite films. The structural and morphological properties of the interfacial monolayers and LB films were investigated using surface pressure-area isotherms, Brewster angle microscopy, polarization modulation infrared reflection-absorption spectroscopy (PM-IRRAS) and quartz crystal microbalance.
View Article and Find Full Text PDFJ Org Chem
September 2025
School of Chemical and Biopharmaceutical Sciences, Technological University Dublin, City Campus, Grangegorman, Dublin D07 EWV4, Ireland.
A series of unsymmetrically substituted BODIPY dyes featuring fused benzo- or naphtho-fragments on one pyrrolic unit were synthesized from the corresponding pyrrolic precursors. The synthetic route was optimized using a modular approach based on the condensation of formylpyrroles with alkylpyrroles, enabling the identification of precursor combinations that minimize byproduct formation and improve preparative yields. The resulting benzo- and naphtho-fused BODIPYs display intense fluorescence in the red region, with emission maxima spanning 590-680 nm and fluorescence quantum yields ranging from 0.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2025
Faculty of Chemistry, Wrocław University of Science and Technology, Wyb. Wyspiańskiego 27, PL-50370 Wrocław, Poland.
Computer simulations play an essential role in the interpretation of experimental multiphoton absorption spectra. In addition, models derived from theory allow for the establishment of "structure-property" relationships. This work contributes to these efforts and presents the results of an analysis of two- and three-photon absorptions for a set comprising 450 conjugated molecules performed at the CAM-B3LYP/aug-cc-pVDZ level.
View Article and Find Full Text PDFACS Omega
September 2025
Tecnologico de Monterrey, Escuela de Ingeniería y Ciencias, Ave. Eugenio Garza Sada 2501, Monterrey 64849, Mexico.
In this work, carbon nanodots (CNDs) were synthesized via a pyrolysis carbonization method using petals. The synthesized CNDs exhibit optical absorption in the UV region, with a tail extending out into the visible range. When these CNDs interact with Ho ions through charge transfer processes, they form an RE-CNDs hybrid (Rare Earth-CNDs hybrid), resulting in fluorescence quenching in an aqueous solution.
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