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Inorganic/organic nanocomposite counter electrodes comprised of sheetlike CoS nanoparticles dispersed in polystyrenesulfonate-doped poly(3,4-ethylenedioxythiophene (CoS/PEDOT:PSS) offer a synergistic effect on catalytic performance toward the reduction of triiodide for dye-sensitized solar cells (DSSCs), yielding 5.4% power conversion efficiency, which is comparable to that of the conventional platinum counter electrode (6.1%). The electrochemical impedance spectroscopy (EIS) and cyclic voltammetry measurements revealed that the composite counter electrodes exhibited better catalytic activity, fostering rate of triiodide reduction, than that of pristine PEDOT: PSS electrode. The simple preparation of composite (CoS/PEDOT:PSS) electrode at low temperature with improved electrocatalytic properties are feasible to apply in flexible substrates, which is at most urgency for developing novel counter electrodes for lightweight flexible solar cells.
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http://dx.doi.org/10.1021/am2003735 | DOI Listing |
Phys Chem Chem Phys
September 2025
School of Chemistry and Chemical Engineering, Key Laboratory of Theoretical Organic Chemistry and Function Molecule of Ministry of Education, Hunan University of Science and Technology, Xiangtan, 411201, P. R. China.
Additive assisted strategies play a crucial role in optimizing the morphology and improving the performance of organic solar cells (OSCs), yet the molecular-level mechanisms remain unclear. Here, we employ molecular dynamics (AIMD) and density functional theory (DFT) to elucidate the influence of typical additives of 1,8-diiodooctane (DIO) and 3,5-dichlorobromobenzene (DCBB) on molecular packing, electronic structures, and charge transport. It can be observed that both additives can enhance the stacking properties of the donor and acceptor materials, yet they have different effects on the local electrostatic environment.
View Article and Find Full Text PDFNanomicro Lett
September 2025
College of New Materials and New Energies, Shenzhen Technology University, Lantian Road 3002, Pingshan, 518118, Shenzhen, People's Republic of China.
The introduction of two-dimensional (2D) perovskite layers on top of three-dimensional (3D) perovskite films enhances the performance and stability of perovskite solar cells (PSCs). However, the electronic effect of the spacer cation and the quality of the 2D capping layer are critical factors in achieving the required results. In this study, we compared two fluorinated salts: 4-(trifluoromethyl) benzamidine hydrochloride (4TF-BA·HCl) and 4-fluorobenzamidine hydrochloride (4F-BA·HCl) to engineer the 3D/2D perovskite films.
View Article and Find Full Text PDFJ Chem Phys
September 2025
Quantum Chemistry Division, Yokohama City University, Seto 22-2, Kanazawa-Ku, Yokohama 236-0027, Kanagawa, Japan.
Perovskite-silicon tandem solar cells have attracted considerable attention owing to their high power conversion efficiency (PCE), which exceeds the limits of single-junction devices. This study focused on lead-free tin-based perovskites with iodine-bromine mixed anions. Bromide perovskites have a wide bandgap; therefore, they are promising light absorbers for perovskite-silicon tandem solar cells.
View Article and Find Full Text PDFAdv Mater
September 2025
College of Smart Materials and Future Energy, and State Key Laboratory of Photovoltaic Science and Technology, Fudan University, Shanghai, 200438, China.
Nonfullerene acceptor-based organic solar cells have recently taken a milestone leap with power conversion efficiencies approaching 20%. A key to further boost the efficiencies up to the Shockley-Queisser limit rests upon attaining a delicate balance between exciton dissociation and charge transport. This perspective presents two seminal and reciprocal strategies developed by our group and others to reconcile the intricacy of charge carrier dynamics, spanning from intrinsic molecular structure design to extrinsic dopant exploitation.
View Article and Find Full Text PDFAdv Mater
September 2025
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006, China.
Perovskite materials have revolutionized optoelectronics by virtue of their tunable bandgaps, exceptional optoelectronic properties, and structural flexibility. Notably, the state-of-the-art performance of perovskite solar cells has reached 27%, making perovskite materials a promising candidate for next-generation photovoltaic technology. Although numerous reviews regarding perovskite materials have been published, the existing reviews generally focus on individual material systems (e.
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