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Article Abstract
New aminonaphthalimide imidazolium podands, which worked as luminescence chemosensors for selectively sensing nucleoside polyphosphates through a "turn-on" manner, were prepared for fluorescent imaging of ADP and ATP in living cells.
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Aminonaphthalimide-based imidazolium podands for turn-on fluorescence sensing of nucleoside polyphosphates.
Org Biomol Chem
June 2010
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116012, China.
New aminonaphthalimide imidazolium podands, which worked as luminescence chemosensors for selectively sensing nucleoside polyphosphates through a "turn-on" manner, were prepared for fluorescent imaging of ADP and ATP in living cells.
View Article and Find Full Text PDFIntramolecular C-H...Ccarbene hydrogen bonds and competing interactions in monoprotonated tripodal carbenes.
J Comput Chem
April 2004
Department Of Chemistry, Cardiff University, University of Strathclyde, Cardiff CF10 3TB Glasgow G1 1XL, Wales, Scotland, UK.
The anionic tripodal N-heterocyclic carbene (C3N2H3)3BH- first prepared by Fehlhammer, together with three neutral variants, (C3N2H3)3CH, (C3N2H3)3P, and (C3N2H3)3SiH, have been studied using quantum chemical methods. Isodesmic reactions are used to deduce that the phosphine-bridgehead species in particular has a large-resonance stabilization energy. All the podands undergo substantial conformational change on excitation to the lowest triplet electronic state, with effective localization of the excitation on one of the heterocyclic rings, dearomatizing it.
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