Cobalt complexes have previously been reported to exhibit high faradaic efficiency in reducing CO to CO. Herein, we synthesized capsule-like cobalt-polypyridine diamine complexes [Co(L)](BF) () and [Co(L) (CHCN)](BF) () as catalysts for the electrocatalytic reduction of CO. Under catalytic conditions, complexes and demonstrated the electrocatalytic reduction of CO to CO in the presence or absence of CHOH as a proton source.
View Article and Find Full Text PDFIntroduction: This study was conducted to assess the effect of mixed isoacid (MI) supplementation on fermentation characteristics, nutrient apparent digestibility, growth performance, and rumen bacterial community in yaks.
Methods: A 72-h fermentation experiment was performed on an ANKOM RF gas production system. MI was added to five treatments at doses of 0, 0.
This experiment was conducted to investigate the effects of methionine analogues 2-hydroxy-4-methylthio butanoic acid isopropyl ester (HBMi) on growth performance, nutrient apparent digestibility, serum metabolite, serum free amino acids, and rumen fermentation parameters of yaks. Twenty-four male Maiwa yaks (252.79 ± 15.
View Article and Find Full Text PDFPetroleum refinery wastewater (PRWW) that contains recalcitrant components as the major portion of constituents is difficult to treat by conventional biological processes. An effective and economical biological treatment process was established to treat industrial PRWW with an influent COD of over 2500 mg L in this research. This process is mainly composed of internal circulation biological aerated filter (ICBAF), hydrolysis acidfication (HA), two anaerobic-aerobic (A/O) units, a membrane biological reactor (MBR), and ozone-activated carbon (O-AC) units.
View Article and Find Full Text PDFIn this study, an internal circulation biological aerated filter (ICBAF) reactor was applied to pretreat refinery wastewater containing large amounts of organic pollutants. According to the composition change of inlet-and-outlet water, the main organic pollutants, including micromolecular organic-acids, aldehydes, ketones, phenols, and so forth, degraded well in ICBAF unit. The concentration of organic acids, alcohols, and esters changed from 648 to 90 mg/L, 130 to 90 mg/L, and 158 to 228 mg/L, respectively.
View Article and Find Full Text PDFBiol Trace Elem Res
November 2010
The aim of this study was to evaluate the impact of three different chromium forms--chromic chloride (CrCl3), chromium picolinate (CrPic), and a newly synthesized complex of chromium chelated with small peptides (CrSP)--on protein metabolism in vitro. In cultured skeletal muscle cells, CrSP was able to increase the basal and insulin-stimulated levels of protein deposition in skeletal muscles cells. CrCl3 and CrPic augmented insulin-stimulated protein synthesis.
View Article and Find Full Text PDFThe aim of this study was to evaluate the impact of three different chromium forms as chromic chloride (CrCl), chromium picolinate (CrPic), and a newly synthesized complex of chromium chelated with small peptides (CrSP) on glucose uptake and metabolism in vitro. In cultured skeletal muscle cells, chromium augmented insulin-stimulated glucose uptake and metabolism as assessed by a reduced glucose concentration of culture medium. At the molecular level, insulin significantly increased the mRNA levels of insulin receptor (IR), glucose transporter 4 (GLUT4), glycogen synthase (GS), and uncoupling protein-3 (UCP3), and these impacts can be enhanced by the addition of chromium, especially in the form of CrSP.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
August 2002
There are two fluorescence peaks at 350 and 700 nm for tryptophane in pH 7.43 Tris buffer solution, as the excited wavelength is at 296 nm. The fluorescence peak at 700 nm is a nonlinear 1/2 fraction frequency fluorescence peak for tryptophane.
View Article and Find Full Text PDF