Employment of l-Citrulline as an Effective Molecular Bridge for Regulating the Buried Interface of Perovskite Solar Cells to Achieve High Efficiency and Good Stability.

Suppressing the defects from SnO and perovskite interface is essential for the fabrication of large-area n-i-p perovskite solar cells (PSCs) with the needed lifetime and efficiency for commercialization. Here, we report the employment of l-citrulline (CIT), which has amino acid (─COOH, ─NH) and urea (─NH─CO─NH) groups, during SnO colloidal dispersion to function as a molecular bridge to modulate the SnO/perovskite buried interface. The amino acid group can effectively coordinate with Sn to passivate the oxygen vacancy defects of SnO, and the urea group can interact with uncoordinated Pb and I.

Efficient red thermally activated delayed fluorescence emitters achieved through precise control of excited state energy levels.

The variety of highly efficient red/near-infrared (NIR) materials with thermally activated delayed fluorescence (TADF) feature is extremely limited so far, and it is necessary to expand the candidate pool of excellent red/deep-red emitters. However, how to control the energy level alignment of the CT (singlet charge transfer) state and the LE (triplet local excitation) state to improve the emission efficiency of materials remains a challenge. Herein, based on our previously reported green fluorescent material 67dTPA-FQ, three new donor-acceptor type TADF materials (TQ-oMeOTPA, TsQ-oMeOTPA and SQ-oMeOTPA) were designed by introducing 4,4'-dimethoxy triphenylamine (MeOTPA) as the donor, and introduced S atoms on the acceptors to enhance the spin-orbit coupling (SOC) and CT effects.

Effect of Jiawei Tongqiao Huoxue decoction in basilar artery dolichoectasia mice through yes-associated protein/transcriptional co-activator with PDZ-binding motif pathway.

Ethnopharmacological Relevance: The Jiawei Tongqiao Huoxue decoction (JTHD), composed of Acorus calamus var. angustatus Besser, Paeonia lactiflora Pall., Conioselinum anthriscoides 'Chuanxiong', Prunus persica (L.